Lanthanide metal-organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionElectronic supplementary information (ESI) available. CCDC 1035915-1035919. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ta00061k
Five lanthanide metal-organic frameworks, [Ln( L )(H 2 O)(NMP)]·1.5H 2 O (Ln = Ce ( 1 ), Pr ( 2 ); H 3 L = 1,3,5-tris(4-carboxyphenyl-1-ylmethyl)-2,4,6-trimethylbenzene), and [Ln 2 ( L ) 2 (H 2 O) 3 ]·2H 2 O (Ln = Eu ( 3 ), Tm ( 4 ), Yb ( 5 )), have been synthesized and characterized. Complexes 1-5...
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| creator | Wang, Xiaoqing Zhang, Liangliang Yang, Jie Liu, Fuling Dai, Fangna Wang, Rongming Sun, Daofeng |
| description | Five lanthanide metal-organic frameworks, [Ln(
L
)(H
2
O)(NMP)]·1.5H
2
O (Ln = Ce (
1
), Pr (
2
); H
3
L
= 1,3,5-tris(4-carboxyphenyl-1-ylmethyl)-2,4,6-trimethylbenzene), and [Ln
2
(
L
)
2
(H
2
O)
3
]·2H
2
O (Ln = Eu (
3
), Tm (
4
), Yb (
5
)), have been synthesized and characterized. Complexes
1-5
exhibit similar 1D channels through the linkage of Ln-carboxylate chains with the backbones of H
3
L
ligands. The channels for complexes
1
and
2
are occupied by coordinated NMP molecules.
3
shows potential application for the luminescence sensing of small organic molecules. Moreover,
5
exhibits selective adsorption of CO
2
over N
2
and CH
4
and catalytic activities toward the cyanosilylation reaction.
Lanthanide MOFs with fluorescent sensing and selective adsorption have been synthesized and characterized based on a novel flexible ligand. |
| doi_str_mv | 10.1039/c5ta00061k |
| format | Article |
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L
)(H
2
O)(NMP)]·1.5H
2
O (Ln = Ce (
1
), Pr (
2
); H
3
L
= 1,3,5-tris(4-carboxyphenyl-1-ylmethyl)-2,4,6-trimethylbenzene), and [Ln
2
(
L
)
2
(H
2
O)
3
]·2H
2
O (Ln = Eu (
3
), Tm (
4
), Yb (
5
)), have been synthesized and characterized. Complexes
1-5
exhibit similar 1D channels through the linkage of Ln-carboxylate chains with the backbones of H
3
L
ligands. The channels for complexes
1
and
2
are occupied by coordinated NMP molecules.
3
shows potential application for the luminescence sensing of small organic molecules. Moreover,
5
exhibits selective adsorption of CO
2
over N
2
and CH
4
and catalytic activities toward the cyanosilylation reaction.
Lanthanide MOFs with fluorescent sensing and selective adsorption have been synthesized and characterized based on a novel flexible ligand.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c5ta00061k</identifier><language>eng</language><creationdate>2015-06</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Xiaoqing</creatorcontrib><creatorcontrib>Zhang, Liangliang</creatorcontrib><creatorcontrib>Yang, Jie</creatorcontrib><creatorcontrib>Liu, Fuling</creatorcontrib><creatorcontrib>Dai, Fangna</creatorcontrib><creatorcontrib>Wang, Rongming</creatorcontrib><creatorcontrib>Sun, Daofeng</creatorcontrib><title>Lanthanide metal-organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionElectronic supplementary information (ESI) available. CCDC 1035915-1035919. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ta00061k</title><description>Five lanthanide metal-organic frameworks, [Ln(
L
)(H
2
O)(NMP)]·1.5H
2
O (Ln = Ce (
1
), Pr (
2
); H
3
L
= 1,3,5-tris(4-carboxyphenyl-1-ylmethyl)-2,4,6-trimethylbenzene), and [Ln
2
(
L
)
2
(H
2
O)
3
]·2H
2
O (Ln = Eu (
3
), Tm (
4
), Yb (
5
)), have been synthesized and characterized. Complexes
1-5
exhibit similar 1D channels through the linkage of Ln-carboxylate chains with the backbones of H
3
L
ligands. The channels for complexes
1
and
2
are occupied by coordinated NMP molecules.
3
shows potential application for the luminescence sensing of small organic molecules. Moreover,
5
exhibits selective adsorption of CO
2
over N
2
and CH
4
and catalytic activities toward the cyanosilylation reaction.
Lanthanide MOFs with fluorescent sensing and selective adsorption have been synthesized and characterized based on a novel flexible ligand.</description><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkM1PAjEQxVejiQS5eDcZb3pY7Iog68HLApHExIPeydidhUo_Nm1B-e-dFZWDiZ6m0_7mvddJkpNMdDPRyy9lP6IQYpAt95PWleiL9OY6Hxz8nIfDo6QTwiszYshcnrf27h7QxgVaVRIYiqhT5-fcSqg8GnpzfhlAOhtRWWXngGDdmjRUmt7ViybQivESKudBr4yyFCRZSRDIhmbAVRAMag3fusZpkitNAZq5QNxFtSbAMjhfR-XsuLnyroHDqq41GWJ_vwFl2cZgw8D5-Gl6AbhGpZFzdKEoRgXwHvp51k-3Ne_ChHMx-ekl_SbwD7Wbe6wXrF5iRBaFYjrheODigjzQzn3rxhkJRo_TW_i96OPksEIdqPNV28npZPxc3Kc-yFntleHYsx3eaydnf73P6rLq_afxAcFDnpY</recordid><startdate>20150609</startdate><enddate>20150609</enddate><creator>Wang, Xiaoqing</creator><creator>Zhang, Liangliang</creator><creator>Yang, Jie</creator><creator>Liu, Fuling</creator><creator>Dai, Fangna</creator><creator>Wang, Rongming</creator><creator>Sun, Daofeng</creator><scope/></search><sort><creationdate>20150609</creationdate><title>Lanthanide metal-organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionElectronic supplementary information (ESI) available. CCDC 1035915-1035919. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ta00061k</title><author>Wang, Xiaoqing ; Zhang, Liangliang ; Yang, Jie ; Liu, Fuling ; Dai, Fangna ; Wang, Rongming ; Sun, Daofeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5ta00061k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xiaoqing</creatorcontrib><creatorcontrib>Zhang, Liangliang</creatorcontrib><creatorcontrib>Yang, Jie</creatorcontrib><creatorcontrib>Liu, Fuling</creatorcontrib><creatorcontrib>Dai, Fangna</creatorcontrib><creatorcontrib>Wang, Rongming</creatorcontrib><creatorcontrib>Sun, Daofeng</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xiaoqing</au><au>Zhang, Liangliang</au><au>Yang, Jie</au><au>Liu, Fuling</au><au>Dai, Fangna</au><au>Wang, Rongming</au><au>Sun, Daofeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lanthanide metal-organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionElectronic supplementary information (ESI) available. CCDC 1035915-1035919. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ta00061k</atitle><date>2015-06-09</date><risdate>2015</risdate><volume>3</volume><issue>24</issue><spage>12777</spage><epage>12785</epage><pages>12777-12785</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Five lanthanide metal-organic frameworks, [Ln(
L
)(H
2
O)(NMP)]·1.5H
2
O (Ln = Ce (
1
), Pr (
2
); H
3
L
= 1,3,5-tris(4-carboxyphenyl-1-ylmethyl)-2,4,6-trimethylbenzene), and [Ln
2
(
L
)
2
(H
2
O)
3
]·2H
2
O (Ln = Eu (
3
), Tm (
4
), Yb (
5
)), have been synthesized and characterized. Complexes
1-5
exhibit similar 1D channels through the linkage of Ln-carboxylate chains with the backbones of H
3
L
ligands. The channels for complexes
1
and
2
are occupied by coordinated NMP molecules.
3
shows potential application for the luminescence sensing of small organic molecules. Moreover,
5
exhibits selective adsorption of CO
2
over N
2
and CH
4
and catalytic activities toward the cyanosilylation reaction.
Lanthanide MOFs with fluorescent sensing and selective adsorption have been synthesized and characterized based on a novel flexible ligand.</abstract><doi>10.1039/c5ta00061k</doi><tpages>9</tpages></addata></record> |
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| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Lanthanide metal-organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionElectronic supplementary information (ESI) available. CCDC 1035915-1035919. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ta00061k |
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