Enhancing thermo-stability to ethylene polymerization: synthesis, characterization and the catalytic behavior of 1-(2,4-dibenzhydryl-6-chlorophenylimino)-2-aryliminoacenaphthylnickel halidesElectronic supplementary information (ESI) available. CCDC 1422645 and 1422646 contain the supplementary crystallographic data for Ni2 and Ni5. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ra18257c
A series of 1-(2,4-dibenzhydryl-6-chlorophenylimino)-2-aryliminoacenaphthylene derivatives ( L1-L5 ) was synthesized and reacted with nickel halides to form the corresponding nickel complexes LNiX 2 (X = Br, Ni1-Ni5 ; X = Cl, Ni6-Ni10 ). The molecular structures of representative complexes Ni2 and N...
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