Tuning the optoelectronic properties of core-substituted naphthalene diimides by the selective conversion of imides to monothioimidesElectronic supplementary information (ESI) available: Experimental details, NMR spectra, MALDI-TOF MS spectra, XRD of RF2-1S, and computational data. CCDC 1056142. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ra05920h
Selective sulfur substitution of the distal carbonyls of a core-substituted naphthalene diimide was obtained when a combination of core and imide substituents were used. The substituents appear to inhibit thionation of the proximal carbonyl by steric hindrance. Each thionation caused a 50 nm bathoch...
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