Tripodal hydrogen bond donor binding with sulfonic acid enables ring-opening polymerization

H-bond donor (HBD) and Brønsted acid (BA) co-catalysis (HBD-BA) performed ring-opening polymerization (ROP) of cyclic esters in solution at room temperature. The HBD-BA strategy using thiophosphoric triamide (TPTA) binding with methanesulfonic acid (MSA) enabled the ROP of l -lactide (LA) to polylac...

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Veröffentlicht in:	Polymer chemistry 2016-02, Vol.7 (7), p.1368-1374
Hauptverfasser:	Li, Xiaopei, Zhang, Qiguo, Li, Zhenjiang, Xu, Songquan, Zhao, Chengxu, Chen, Cheng, Zhi, Xu, Wang, Huiying, Zhu, Ning, Guo, Kai
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Carbonates Catalysis Esters Hydrogen bonds Manganese Polymerization Sulfonates
Online-Zugang:	Volltext
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