Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalizationElectronic supplementary information (ESI) available. CCDC 1054103 (3c), 1401266 (3p) and 1054104 (4c). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5nj01706h
Synthesis of polycyclic amines was achieved by benzoic acid catalysed reaction of 1-aryl THIQs and 1-aryl trypolines with o -allyl salicylaldehydes through the in situ generated azomethine ylide intermediates that undergo intramolecular [3+2]-cycloadditions with four new stereogenic centers in excel...
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| creator | Pavan Kumar, Chottanahalli S Harsha, Kachigere B Sandhya, Nagarakere C Ramesha, Ajjalli B Mantelingu, Kempegowda Rangappa, Kanchugarakoppal S |
| description | Synthesis of polycyclic amines was achieved by benzoic acid catalysed reaction of 1-aryl THIQs and 1-aryl trypolines with
o
-allyl salicylaldehydes through the
in situ
generated azomethine ylide intermediates that undergo intramolecular [3+2]-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.
Construction of polycyclic amines
via
C-H functionalization and 3+2 cycloaddition with high diastereoselectivities was achieved under mild conditions. |
| doi_str_mv | 10.1039/c5nj01706h |
| format | Article |
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o
-allyl salicylaldehydes through the
in situ
generated azomethine ylide intermediates that undergo intramolecular [3+2]-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.
Construction of polycyclic amines
via
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o
-allyl salicylaldehydes through the
in situ
generated azomethine ylide intermediates that undergo intramolecular [3+2]-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.
Construction of polycyclic amines
via
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o
-allyl salicylaldehydes through the
in situ
generated azomethine ylide intermediates that undergo intramolecular [3+2]-cycloadditions with four new stereogenic centers in excellent diastereoselectivities under simple and mild conditions.
Construction of polycyclic amines
via
C-H functionalization and 3+2 cycloaddition with high diastereoselectivities was achieved under mild conditions.</abstract><doi>10.1039/c5nj01706h</doi><tpages>8</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Highly diastereoselective synthesis of polycyclic amines via redox neutral C-H functionalizationElectronic supplementary information (ESI) available. CCDC 1054103 (3c), 1401266 (3p) and 1054104 (4c). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5nj01706h |
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