Using degrees of rate control to improve selective -butane oxidation over model MOF-encapsulated catalysts: sterically-constrained AgPd(111)

Metal nanoparticles encapsulated within metal organic frameworks (MOFs) offer steric restrictions near the catalytic metal that can improve selectivity, much like in enzymes. A microkinetic model is developed for the regio-selective oxidation of n -butane to 1-butanol with O 2 over a model for MOF-e...

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Veröffentlicht in:	Faraday discussions 2016-07, Vol.188, p.21-38
Hauptverfasser:	Dix, Sean T, Scott, Joseph K, Getman, Rachel B, Campbell, Charles T
Format:	Artikel
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