Regioselectivity in C-H activation: reagent control in cyclometallation of 2-(1-naphthyl)-pyridineElectronic supplementary information (ESI) available: X-ray data in cif format. CCDC 1404269 and 1404270. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt04068j

2-(1-Naphthyl)-pyridine ( 1 ) possesses sp 2 C-H bonds in both the γ- and δ-positions and is therefore a suitable substrate for studying the cyclometallation selectivity with different reagents and conditions. Such selectivity studies are reported. Based on deuterium-exchange experiments it is concl...

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Hauptverfasser:	Kondrashov, Mikhail, Provost, David, Wendt, Ola F
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