Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silyleneElectronic supplementary information (ESI) available: Experimental description of catalysis, solution-phase and solid-state NMR spectra, and computational results. See DOI: 10.1039/c5dt02844b

An electrophilic, coordinatively unsaturated rhodium complex supported by borate-linked oxazoline, oxazoline-coordinated silylene, and N-heterocyclic carbene donors [{κ 3 -N,Si,C-PhB(Ox Me2 )(Ox Me2 SiHPh)Im Mes }Rh(H)CO][HB(C 6 F 5 ) 3 ] ( 2 , Ox Me2 = 4,4-dimethyl-2-oxazoline; Im Mes = 1-mesitylim...

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Hauptverfasser:	Xu, Songchen, Boschen, Jeffery S, Biswas, Abhranil, Kobayashi, Takeshi, Pruski, Marek, Windus, Theresa L, Sadow, Aaron D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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