Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerizationElectronic supplementary information (ESI) available. CCDC 1041025-1041028. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt02570b

A new tridentate amidine 2-[Ph 2 P(O)]C 6 H 4 NHC( t Bu)&z.dbd;N(2,6-Me 2 C 6 H 3 ) ( 1 ) bearing a side chain pendant Ph 2 P&z.dbd;O group was synthesized and proved to be a suitable ligand for coordination to rare-earths ions. Bis(alkyl) complexes {2-[Ph 2 P(O)]C 6 H 4 NC( t Bu)N(2,6-Me 2...

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Hauptverfasser:	Tolpygin, Aleksei O, Glukhova, Tatyana A, Cherkasov, Anton V, Fukin, Georgy K, Aleksanyan, Diana V, Cui, Dongmei, Trifonov, Alexander A
Format:	Artikel
Sprache:	eng
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