Spin transitions in bis(amidinato)-N-heterocyclic carbene iron(ii) and iron(iii) complexesThis paper is dedicated in memoriam to Gregory L. Hillhouse.Electronic supplementary information (ESI) available: General considerations, computational methods, synthetic procedures and characterization for all new complexes. CCDC 900881, 927786-927788 for 2a, 927790-927794 for 3. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt02440d

In contrast to high spin pyridyl diimine iron( ii ) dichloride complexes, analogous bis(amidinato)-N-heterocyclic carbene iron( ii ) and iron( iii ) complexes demonstrate complex magnetic behaviour. In the solid state, they are best described as intermediate spin complexes at low temperatures that d...

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Hauptverfasser:	Drake, Jessica L, Kaplan, Hilan Z, Wilding, Matthew J. T, Li, Bo, Byers, Jeffery A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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