Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexesElectronic supplementary information (ESI) available: Details of synthesis of lipophilic Ru complexes, physical measurements and additional experimental data. CCDC 1050758. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00793c
A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O 2 evolution reaction using cerium( iv ) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O 2 evol...
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creator | Koshiyama, Tomomi Kanda, Nao Iwata, Koki Honjo, Masayuki Asada, Sana Hatae, Tatsuru Tsuji, Yasuhiro Yoshida, Masaki Okamura, Masaya Kuga, Reiko Masaoka, Shigeyuki Ohba, Masaaki |
description | A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O
2
evolution reaction using cerium(
iv
) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O
2
evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.
An O
2
evolution catalyst system based on liposomes and lipophilic Ru(
ii
) complexes was fabricated with regulating the surrounding environment of reaction centre. |
doi_str_mv | 10.1039/c5dt00793c |
format | Article |
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2
evolution reaction using cerium(
iv
) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O
2
evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.
An O
2
evolution catalyst system based on liposomes and lipophilic Ru(
ii
) complexes was fabricated with regulating the surrounding environment of reaction centre.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c5dt00793c</identifier><language>eng</language><creationdate>2015-08</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Koshiyama, Tomomi</creatorcontrib><creatorcontrib>Kanda, Nao</creatorcontrib><creatorcontrib>Iwata, Koki</creatorcontrib><creatorcontrib>Honjo, Masayuki</creatorcontrib><creatorcontrib>Asada, Sana</creatorcontrib><creatorcontrib>Hatae, Tatsuru</creatorcontrib><creatorcontrib>Tsuji, Yasuhiro</creatorcontrib><creatorcontrib>Yoshida, Masaki</creatorcontrib><creatorcontrib>Okamura, Masaya</creatorcontrib><creatorcontrib>Kuga, Reiko</creatorcontrib><creatorcontrib>Masaoka, Shigeyuki</creatorcontrib><creatorcontrib>Ohba, Masaaki</creatorcontrib><title>Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexesElectronic supplementary information (ESI) available: Details of synthesis of lipophilic Ru complexes, physical measurements and additional experimental data. CCDC 1050758. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00793c</title><description>A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O
2
evolution reaction using cerium(
iv
) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O
2
evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.
An O
2
evolution catalyst system based on liposomes and lipophilic Ru(
ii
) complexes was fabricated with regulating the surrounding environment of reaction centre.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkcFPwjAUxqfRREUv3k2eN0gEu4054TogciJB76R2b1DTtUvbLezsP24pBA4meup7fd97v--1QXAfkkFI4tEzS3JLSDqK2XlwHQ7TtD-K4uHFMY5eroIbY74IiSKSRNdn30tc14JariSoAigw1Lwuu7zp9XPNG5SwiAAbJWqv0UiZD2rD5RqYKitluEWz6xbcJapEoDL3SbXhgjPQtd2gdGO9XuAWzVQgs1pJVzV15e5KlJbqFrgslC73hrrT93kPaEO5oJ8CxzBB62LPMq10Qw0_gg-sZX2CPEG1aQ1nVECJ1NTaU4y3R_Oc7yCuhtvKLe0NCMippQPIskkGIUlImrwOYKY0OCu-j-nWOJ1Qa00dkvkG5xqy-QycTjlXGvC03n4dMIgwWczH8PurboPLggqDd4ezEzzMph_ZW18btqqcM_cuq5M87gSPf9VXVV7E_834ATLRuVI</recordid><startdate>20150818</startdate><enddate>20150818</enddate><creator>Koshiyama, Tomomi</creator><creator>Kanda, Nao</creator><creator>Iwata, Koki</creator><creator>Honjo, Masayuki</creator><creator>Asada, Sana</creator><creator>Hatae, Tatsuru</creator><creator>Tsuji, Yasuhiro</creator><creator>Yoshida, Masaki</creator><creator>Okamura, Masaya</creator><creator>Kuga, Reiko</creator><creator>Masaoka, Shigeyuki</creator><creator>Ohba, Masaaki</creator><scope/></search><sort><creationdate>20150818</creationdate><title>Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexesElectronic supplementary information (ESI) available: Details of synthesis of lipophilic Ru complexes, physical measurements and additional experimental data. CCDC 1050758. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00793c</title><author>Koshiyama, Tomomi ; Kanda, Nao ; Iwata, Koki ; Honjo, Masayuki ; Asada, Sana ; Hatae, Tatsuru ; Tsuji, Yasuhiro ; Yoshida, Masaki ; Okamura, Masaya ; Kuga, Reiko ; Masaoka, Shigeyuki ; Ohba, Masaaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5dt00793c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Koshiyama, Tomomi</creatorcontrib><creatorcontrib>Kanda, Nao</creatorcontrib><creatorcontrib>Iwata, Koki</creatorcontrib><creatorcontrib>Honjo, Masayuki</creatorcontrib><creatorcontrib>Asada, Sana</creatorcontrib><creatorcontrib>Hatae, Tatsuru</creatorcontrib><creatorcontrib>Tsuji, Yasuhiro</creatorcontrib><creatorcontrib>Yoshida, Masaki</creatorcontrib><creatorcontrib>Okamura, Masaya</creatorcontrib><creatorcontrib>Kuga, Reiko</creatorcontrib><creatorcontrib>Masaoka, Shigeyuki</creatorcontrib><creatorcontrib>Ohba, Masaaki</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Koshiyama, Tomomi</au><au>Kanda, Nao</au><au>Iwata, Koki</au><au>Honjo, Masayuki</au><au>Asada, Sana</au><au>Hatae, Tatsuru</au><au>Tsuji, Yasuhiro</au><au>Yoshida, Masaki</au><au>Okamura, Masaya</au><au>Kuga, Reiko</au><au>Masaoka, Shigeyuki</au><au>Ohba, Masaaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexesElectronic supplementary information (ESI) available: Details of synthesis of lipophilic Ru complexes, physical measurements and additional experimental data. CCDC 1050758. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00793c</atitle><date>2015-08-18</date><risdate>2015</risdate><volume>44</volume><issue>34</issue><spage>15126</spage><epage>15129</epage><pages>15126-15129</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O
2
evolution reaction using cerium(
iv
) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O
2
evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.
An O
2
evolution catalyst system based on liposomes and lipophilic Ru(
ii
) complexes was fabricated with regulating the surrounding environment of reaction centre.</abstract><doi>10.1039/c5dt00793c</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
title | Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexesElectronic supplementary information (ESI) available: Details of synthesis of lipophilic Ru complexes, physical measurements and additional experimental data. CCDC 1050758. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00793c |
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