Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2]−This article is dedicated to the memory of Professor Kenneth (Ken) Wade.Electronic supplementary information (ESI) available: Synthetic procedure to Zr(L)(NMe2)Cl2; crystallographic data. CCDC 850298-850302. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00684h
The anisole-substituted silyl-amide anion, [N(SiMe 2 {C 6 H 4 -2-OMe}) 2 ] − ( L ), has been used as a pincer-type ligand in coordination chemistry. X-ray diffraction data for the lithium salt shows a trimetallic structure consisting of two equivalents of Li( L ) that sequester a molecule of LiCl. T...
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