Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives
Phenols are widely used as starting materials in both industrial and academic society. Dearomatization reactions of phenols provide an efficient way to construct highly functionalized cyclohexadienones. The main challenge to make them asymmetric by catalytic methods is to control the selectivity whi...
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| Veröffentlicht in: | Chemical Society reviews 2016-03, Vol.45 (6), p.157-158 |
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| container_title | Chemical Society reviews |
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| creator | Wu, Wen-Ting Zhang, Liming You, Shu-Li |
| description | Phenols are widely used as starting materials in both industrial and academic society. Dearomatization reactions of phenols provide an efficient way to construct highly functionalized cyclohexadienones. The main challenge to make them asymmetric by catalytic methods is to control the selectivity while overcoming the loss of aromaticity. In this tutorial review, an up to date summary of recent progress in CADA reactions of phenol and aniline derivatives is presented.
In this tutorial review, an up to date summary of recent progress in catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives is presented. |
| doi_str_mv | 10.1039/c5cs00356c |
| format | Article |
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In this tutorial review, an up to date summary of recent progress in catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives is presented.</description><subject>Aniline</subject><subject>Aniline Compounds - chemistry</subject><subject>Aromaticity</subject><subject>Asymmetry</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Construction industry</subject><subject>Derivatives</subject><subject>Oxidation-Reduction</subject><subject>Phenol</subject><subject>Phenol - chemistry</subject><issn>0306-0012</issn><issn>1460-4744</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkctLw0AQxhdRbK1evCs5ViE6-0h291jiEwoeVDyGzWaKkTzqblqof71bW-vRwzAzzG8-mG8IOaVwRYHra5tYD8CT1O6RIRUpxEIKsU-GwCGNASgbkCPvP0JFZcoOyYClUqeasSF5y0xv6lVf2cj4VdNg70JZonFdY_rqK0TXRuNscjO5iBwau-591M2i-Tu2XR2ZtgxR1VWLYc1Vy7CxRH9MDmam9niyzSPyenf7kj3E06f7x2wyja0Qoo-5LuUMkFmFTCnKKCitCqakRFpgOM5YKZOClwU1idW21FLygnFUEhPGBR-R8UZ37rrPBfo-bypvsa5Ni93C51QBiFRSrf5Hg7QClbA1erlBreu8dzjL565qjFvlFPK153mWZM8_nmcBPt_qLooGyx36a3IAzjaA83Y3_Xsa_wYDWYUk</recordid><startdate>20160321</startdate><enddate>20160321</enddate><creator>Wu, Wen-Ting</creator><creator>Zhang, Liming</creator><creator>You, Shu-Li</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160321</creationdate><title>Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives</title><author>Wu, Wen-Ting ; Zhang, Liming ; You, Shu-Li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c444t-39d7f0e2c8e2881210898b2877e1be039ac775b3db1a5c9cd9773b23e87e52343</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aniline</topic><topic>Aniline Compounds - chemistry</topic><topic>Aromaticity</topic><topic>Asymmetry</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Construction industry</topic><topic>Derivatives</topic><topic>Oxidation-Reduction</topic><topic>Phenol</topic><topic>Phenol - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Wen-Ting</creatorcontrib><creatorcontrib>Zhang, Liming</creatorcontrib><creatorcontrib>You, Shu-Li</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical Society reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Wen-Ting</au><au>Zhang, Liming</au><au>You, Shu-Li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives</atitle><jtitle>Chemical Society reviews</jtitle><addtitle>Chem Soc Rev</addtitle><date>2016-03-21</date><risdate>2016</risdate><volume>45</volume><issue>6</issue><spage>157</spage><epage>158</epage><pages>157-158</pages><issn>0306-0012</issn><eissn>1460-4744</eissn><abstract>Phenols are widely used as starting materials in both industrial and academic society. Dearomatization reactions of phenols provide an efficient way to construct highly functionalized cyclohexadienones. The main challenge to make them asymmetric by catalytic methods is to control the selectivity while overcoming the loss of aromaticity. In this tutorial review, an up to date summary of recent progress in CADA reactions of phenol and aniline derivatives is presented.
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| ispartof | Chemical Society reviews, 2016-03, Vol.45 (6), p.157-158 |
| issn | 0306-0012 1460-4744 |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aniline Aniline Compounds - chemistry Aromaticity Asymmetry Catalysis Catalysts Construction industry Derivatives Oxidation-Reduction Phenol Phenol - chemistry |
| title | Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives |
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