On the energetics of cation ordering in tungsten-bronze-type oxidesElectronic supplementary information (ESI) available: Derivation of thermodynamic equations, energetics data in tabular form and data on crystal structures. See DOI: 10.1039/c5cp05119c
Oxides with the tetragonal tungsten bronze (TTB) structure are well-known ferroelectrics that show a large flexibility both with respect to chemical composition and cation ordering. Two of the simplest compounds in this family are lead metaniobate (PbNb 2 O 6 or PN) and strontium barium niobate (Sr...
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