Inverse internal conversion in C below the electron detachment threshold
Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C 4 − molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C 4 − ions with internal energy far...
Gespeichert in:
| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2015-09, Vol.17 (38), p.24732-24737 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 24737 |
|---|---|
| container_issue | 38 |
| container_start_page | 24732 |
| container_title | Physical chemistry chemical physics : PCCP |
| container_volume | 17 |
| creator | Kono, Naoko Furukawa, Takeshi Tanuma, Hajime Matsumoto, Jun Shiromaru, Haruo Azuma, Toshiyuki Najafian, Kaveh Pettersson, Maria Susanne Dynefors, Bertil Hansen, Klavs |
| description | Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C
4
−
molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C
4
−
ions with internal energy far below the detachment threshold by an alternative novel approach, observing the laser wavelength and storage time dependence (ms range) of the total yield of the photo-induced neutrals.
Inverse internal conversion below the electron detachment threshold drives fast the radiative cooling of vibrationally hot C
4
−
isolated in a vacuum. |
| doi_str_mv | 10.1039/c5cp02549d |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c5cp02549d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c5cp02549d</sourcerecordid><originalsourceid>FETCH-rsc_primary_c5cp02549d3</originalsourceid><addsrcrecordid>eNqFzj0LwjAYBOAgCtaPxV2IP6CamLbauSh1dy8xeUsraRKSoPjvLSK66XTHc8shtKBkTQnLNyIVlmzTJJcDFNEkY3FO9snw03fZGE28vxJCaEpZhMqTvoHzgFsdwGmusDAvaY3uDRf4AsrccWgAgwIRXO8SAhdNBzr07sA3RskZGtVceZi_c4qWx8O5KGPnRWVd23H3qL732P999WuvrKzZE5jKSdM</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Inverse internal conversion in C below the electron detachment threshold</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Kono, Naoko ; Furukawa, Takeshi ; Tanuma, Hajime ; Matsumoto, Jun ; Shiromaru, Haruo ; Azuma, Toshiyuki ; Najafian, Kaveh ; Pettersson, Maria Susanne ; Dynefors, Bertil ; Hansen, Klavs</creator><creatorcontrib>Kono, Naoko ; Furukawa, Takeshi ; Tanuma, Hajime ; Matsumoto, Jun ; Shiromaru, Haruo ; Azuma, Toshiyuki ; Najafian, Kaveh ; Pettersson, Maria Susanne ; Dynefors, Bertil ; Hansen, Klavs</creatorcontrib><description>Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C
4
−
molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C
4
−
ions with internal energy far below the detachment threshold by an alternative novel approach, observing the laser wavelength and storage time dependence (ms range) of the total yield of the photo-induced neutrals.
Inverse internal conversion below the electron detachment threshold drives fast the radiative cooling of vibrationally hot C
4
−
isolated in a vacuum.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c5cp02549d</identifier><language>eng</language><ispartof>Physical chemistry chemical physics : PCCP, 2015-09, Vol.17 (38), p.24732-24737</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Kono, Naoko</creatorcontrib><creatorcontrib>Furukawa, Takeshi</creatorcontrib><creatorcontrib>Tanuma, Hajime</creatorcontrib><creatorcontrib>Matsumoto, Jun</creatorcontrib><creatorcontrib>Shiromaru, Haruo</creatorcontrib><creatorcontrib>Azuma, Toshiyuki</creatorcontrib><creatorcontrib>Najafian, Kaveh</creatorcontrib><creatorcontrib>Pettersson, Maria Susanne</creatorcontrib><creatorcontrib>Dynefors, Bertil</creatorcontrib><creatorcontrib>Hansen, Klavs</creatorcontrib><title>Inverse internal conversion in C below the electron detachment threshold</title><title>Physical chemistry chemical physics : PCCP</title><description>Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C
4
−
molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C
4
−
ions with internal energy far below the detachment threshold by an alternative novel approach, observing the laser wavelength and storage time dependence (ms range) of the total yield of the photo-induced neutrals.
Inverse internal conversion below the electron detachment threshold drives fast the radiative cooling of vibrationally hot C
4
−
isolated in a vacuum.</description><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFzj0LwjAYBOAgCtaPxV2IP6CamLbauSh1dy8xeUsraRKSoPjvLSK66XTHc8shtKBkTQnLNyIVlmzTJJcDFNEkY3FO9snw03fZGE28vxJCaEpZhMqTvoHzgFsdwGmusDAvaY3uDRf4AsrccWgAgwIRXO8SAhdNBzr07sA3RskZGtVceZi_c4qWx8O5KGPnRWVd23H3qL732P999WuvrKzZE5jKSdM</recordid><startdate>20150923</startdate><enddate>20150923</enddate><creator>Kono, Naoko</creator><creator>Furukawa, Takeshi</creator><creator>Tanuma, Hajime</creator><creator>Matsumoto, Jun</creator><creator>Shiromaru, Haruo</creator><creator>Azuma, Toshiyuki</creator><creator>Najafian, Kaveh</creator><creator>Pettersson, Maria Susanne</creator><creator>Dynefors, Bertil</creator><creator>Hansen, Klavs</creator><scope/></search><sort><creationdate>20150923</creationdate><title>Inverse internal conversion in C below the electron detachment threshold</title><author>Kono, Naoko ; Furukawa, Takeshi ; Tanuma, Hajime ; Matsumoto, Jun ; Shiromaru, Haruo ; Azuma, Toshiyuki ; Najafian, Kaveh ; Pettersson, Maria Susanne ; Dynefors, Bertil ; Hansen, Klavs</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5cp02549d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kono, Naoko</creatorcontrib><creatorcontrib>Furukawa, Takeshi</creatorcontrib><creatorcontrib>Tanuma, Hajime</creatorcontrib><creatorcontrib>Matsumoto, Jun</creatorcontrib><creatorcontrib>Shiromaru, Haruo</creatorcontrib><creatorcontrib>Azuma, Toshiyuki</creatorcontrib><creatorcontrib>Najafian, Kaveh</creatorcontrib><creatorcontrib>Pettersson, Maria Susanne</creatorcontrib><creatorcontrib>Dynefors, Bertil</creatorcontrib><creatorcontrib>Hansen, Klavs</creatorcontrib><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kono, Naoko</au><au>Furukawa, Takeshi</au><au>Tanuma, Hajime</au><au>Matsumoto, Jun</au><au>Shiromaru, Haruo</au><au>Azuma, Toshiyuki</au><au>Najafian, Kaveh</au><au>Pettersson, Maria Susanne</au><au>Dynefors, Bertil</au><au>Hansen, Klavs</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inverse internal conversion in C below the electron detachment threshold</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><date>2015-09-23</date><risdate>2015</risdate><volume>17</volume><issue>38</issue><spage>24732</spage><epage>24737</epage><pages>24732-24737</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C
4
−
molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C
4
−
ions with internal energy far below the detachment threshold by an alternative novel approach, observing the laser wavelength and storage time dependence (ms range) of the total yield of the photo-induced neutrals.
Inverse internal conversion below the electron detachment threshold drives fast the radiative cooling of vibrationally hot C
4
−
isolated in a vacuum.</abstract><doi>10.1039/c5cp02549d</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2015-09, Vol.17 (38), p.24732-24737 |
| issn | 1463-9076 1463-9084 |
| language | eng |
| recordid | cdi_rsc_primary_c5cp02549d |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Inverse internal conversion in C below the electron detachment threshold |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-23T09%3A43%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Inverse%20internal%20conversion%20in%20C%20below%20the%20electron%20detachment%20threshold&rft.jtitle=Physical%20chemistry%20chemical%20physics%20:%20PCCP&rft.au=Kono,%20Naoko&rft.date=2015-09-23&rft.volume=17&rft.issue=38&rft.spage=24732&rft.epage=24737&rft.pages=24732-24737&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c5cp02549d&rft_dat=%3Crsc%3Ec5cp02549d%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |