Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reactionElectronic supplementary information (ESI) available: Synthetic and crystallographic details for 1 and 2; Tables S1-S3. CCDC 1415404 & 1415405. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ce01680k
SbPh 3 Cl 2 is used to effect a dramatic rearrangment of the ligand sphere and "pancake bonding" in Ce(hfac) 3 (5′-Br-pyDTDA) 2 , by forming a 2 : 1 host-guest complex supported by numerous non-covalent contacts (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-; 5′-Br-pyDTDA = 4-(5′-bromopyri...
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| creator | Mills, Michelle B Hollingshead, Andrew G Maahs, Adam C Soldatov, Dmitriy V Preuss, Kathryn E |
| description | SbPh
3
Cl
2
is used to effect a dramatic rearrangment of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
, by forming a 2 : 1 host-guest complex supported by numerous non-covalent contacts (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-; 5′-Br-pyDTDA = 4-(5′-bromopyrid-2′-yl)-1,2,3,5-dithiadiazolyl). The host-guest complex forms quantitatively in a solvent-free solid-to-solid reaction and crystals are grown by sublimation.
SbPh
3
Cl
2
is used to effect a dramatic rearrangement of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
by forming a 2 : 1 host-guest complex. |
| doi_str_mv | 10.1039/c5ce01680k |
| format | Article |
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3
Cl
2
is used to effect a dramatic rearrangment of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
, by forming a 2 : 1 host-guest complex supported by numerous non-covalent contacts (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-; 5′-Br-pyDTDA = 4-(5′-bromopyrid-2′-yl)-1,2,3,5-dithiadiazolyl). The host-guest complex forms quantitatively in a solvent-free solid-to-solid reaction and crystals are grown by sublimation.
SbPh
3
Cl
2
is used to effect a dramatic rearrangement of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
by forming a 2 : 1 host-guest complex.</description><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c5ce01680k</identifier><language>eng</language><creationdate>2015-10</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Mills, Michelle B</creatorcontrib><creatorcontrib>Hollingshead, Andrew G</creatorcontrib><creatorcontrib>Maahs, Adam C</creatorcontrib><creatorcontrib>Soldatov, Dmitriy V</creatorcontrib><creatorcontrib>Preuss, Kathryn E</creatorcontrib><title>Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reactionElectronic supplementary information (ESI) available: Synthetic and crystallographic details for 1 and 2; Tables S1-S3. CCDC 1415404 & 1415405. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ce01680k</title><description>SbPh
3
Cl
2
is used to effect a dramatic rearrangment of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
, by forming a 2 : 1 host-guest complex supported by numerous non-covalent contacts (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-; 5′-Br-pyDTDA = 4-(5′-bromopyrid-2′-yl)-1,2,3,5-dithiadiazolyl). The host-guest complex forms quantitatively in a solvent-free solid-to-solid reaction and crystals are grown by sublimation.
SbPh
3
Cl
2
is used to effect a dramatic rearrangement of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
by forming a 2 : 1 host-guest complex.</description><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFULFOwzAQDUhIlMLCjnQsCIYUm6RVKWPaikxIpHt1JJfW4NiR7SLK13NtkTogYPKT37t3710UnUvRkyK5vy37JQk5GIq3w6gj08EgHookOY5OvH8VQqZSis7Bc-5tQ059YlDWgK0BQaMJSzSqIiht02r6gJVXZsHUctU0GxRsC4sV-QCBWIGBRsx6q1UVBxtvATjCcuM60VQGZ40qwa9a9mvIBHRrUKa2rtltvp4U-Q3gOyqNL5rtijWnoMBDaCoo3doH1NouHLZL_qwosNQDO4DcSu4eYLYZ9VDIuEh6kGXjDLhnPxUpXH2jfg-mPMLbfvHFgBwMsnwKrLOcwQHtG-wSgyeC8VM-gp_XPo2OatSezr7fbnQxncyyx9j5ct461XD1-V6edKPLv_h5W9XJfx5f-xaf_Q</recordid><startdate>20151012</startdate><enddate>20151012</enddate><creator>Mills, Michelle B</creator><creator>Hollingshead, Andrew G</creator><creator>Maahs, Adam C</creator><creator>Soldatov, Dmitriy V</creator><creator>Preuss, Kathryn E</creator><scope/></search><sort><creationdate>20151012</creationdate><title>Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reactionElectronic supplementary information (ESI) available: Synthetic and crystallographic details for 1 and 2; Tables S1-S3. CCDC 1415404 & 1415405. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ce01680k</title><author>Mills, Michelle B ; Hollingshead, Andrew G ; Maahs, Adam C ; Soldatov, Dmitriy V ; Preuss, Kathryn E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5ce01680k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mills, Michelle B</creatorcontrib><creatorcontrib>Hollingshead, Andrew G</creatorcontrib><creatorcontrib>Maahs, Adam C</creatorcontrib><creatorcontrib>Soldatov, Dmitriy V</creatorcontrib><creatorcontrib>Preuss, Kathryn E</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mills, Michelle B</au><au>Hollingshead, Andrew G</au><au>Maahs, Adam C</au><au>Soldatov, Dmitriy V</au><au>Preuss, Kathryn E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reactionElectronic supplementary information (ESI) available: Synthetic and crystallographic details for 1 and 2; Tables S1-S3. CCDC 1415404 & 1415405. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ce01680k</atitle><date>2015-10-12</date><risdate>2015</risdate><volume>17</volume><issue>41</issue><spage>7816</spage><epage>7819</epage><pages>7816-7819</pages><eissn>1466-8033</eissn><abstract>SbPh
3
Cl
2
is used to effect a dramatic rearrangment of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
, by forming a 2 : 1 host-guest complex supported by numerous non-covalent contacts (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-; 5′-Br-pyDTDA = 4-(5′-bromopyrid-2′-yl)-1,2,3,5-dithiadiazolyl). The host-guest complex forms quantitatively in a solvent-free solid-to-solid reaction and crystals are grown by sublimation.
SbPh
3
Cl
2
is used to effect a dramatic rearrangement of the ligand sphere and "pancake bonding" in Ce(hfac)
3
(5′-Br-pyDTDA)
2
by forming a 2 : 1 host-guest complex.</abstract><doi>10.1039/c5ce01680k</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1466-8033 |
| ispartof | |
| issn | 1466-8033 |
| language | eng |
| recordid | cdi_rsc_primary_c5ce01680k |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reactionElectronic supplementary information (ESI) available: Synthetic and crystallographic details for 1 and 2; Tables S1-S3. CCDC 1415404 & 1415405. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ce01680k |
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