A naphthalimide-based fluorescent sensor for halogenated solvents
A fluorescent sensor for halogenated solvents termed AMN is reported. AMN shows strong fluorescence in most halogenated solvents (QE > 0.1) but weak fluorescence (QE
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (1), p.295-298 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Dai, Li Wu, Di Qiao, Qinglong Yin, Wenting Yin, Jun Xu, Zhaochao |
| description | A fluorescent sensor for halogenated solvents termed
AMN
is reported.
AMN
shows strong fluorescence in most halogenated solvents (QE > 0.1) but weak fluorescence (QE |
| doi_str_mv | 10.1039/c5cc09403h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c5cc09403h</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1800466996</sourcerecordid><originalsourceid>FETCH-LOGICAL-c408t-72b09789fb60a876e55eeb6ffd7d2900390c25c037b510a5771b25d05b1131413</originalsourceid><addsrcrecordid>eNqF0c9LwzAUB_AgipvTi3elRxGqL03z6ziKOmHgRcFbSdLUVdpmJq3gf2_m5jwaCAm8D4-8bxA6x3CDgchbQ40BmQNZHaApJixPaS5eDzd3KlNOcjpBJyG8Q1yYimM0yRiTWAg8RfN50qv1aliptumayqZaBVsldTs6b4Ox_ZAE2wfnkzruqNyb7dUQSXDtZyyHU3RUqzbYs905Qy_3d8_FIl0-PTwW82VqchBDyjMNkgtZawZKcGYptVazuq54lUmIc4DJqAHCNcWgKOdYZ7QCqjEmOMdkhq62fdfefYw2DGXXxAe2reqtG0OJBUAe55Lsf8oZSBCMZZFeb6nxLgRv63Ltm075rxJDuUm3LGhR_KS7iPhy13fUna329DfOCC62wAezr_59D_kGjXt9OA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1760908662</pqid></control><display><type>article</type><title>A naphthalimide-based fluorescent sensor for halogenated solvents</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Dai, Li ; Wu, Di ; Qiao, Qinglong ; Yin, Wenting ; Yin, Jun ; Xu, Zhaochao</creator><creatorcontrib>Dai, Li ; Wu, Di ; Qiao, Qinglong ; Yin, Wenting ; Yin, Jun ; Xu, Zhaochao</creatorcontrib><description>A fluorescent sensor for halogenated solvents termed
AMN
is reported.
AMN
shows strong fluorescence in most halogenated solvents (QE > 0.1) but weak fluorescence (QE<0.01) in most non-halogenated solvents. In chlorinated solvents, the fluorescence intensity decreased with the reduction of chlorine content. On the contrary, in brominated solvents the fluorescence intensity increased with the reduction of bromine content. It is worth mentioning that
AMN
displayed fluorescence emission centered at 520 nm in CCl
4
with a quantum yield of 0.607, at 556 nm in CHCl
3
with a quantum yield of 0.318, at 584 nm in CH
2
Cl
2
with a quantum yield of 0.128, whereas in CHBr
3
was centered at 441 nm with a quantum yield of 0.012.
AMN
was shown to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
halogenated solvents.
AMN
is the first sensor to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
from halogenated solvents.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc09403h</identifier><identifier>PMID: 26691881</identifier><language>eng</language><publisher>England</publisher><subject>Carbon tetrachloride ; Chlorine ; Emission ; Fluorescence ; Halogenated ; Reduction ; Sensors ; Solvents</subject><ispartof>Chemical communications (Cambridge, England), 2016-01, Vol.52 (1), p.295-298</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-72b09789fb60a876e55eeb6ffd7d2900390c25c037b510a5771b25d05b1131413</citedby><cites>FETCH-LOGICAL-c408t-72b09789fb60a876e55eeb6ffd7d2900390c25c037b510a5771b25d05b1131413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26691881$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dai, Li</creatorcontrib><creatorcontrib>Wu, Di</creatorcontrib><creatorcontrib>Qiao, Qinglong</creatorcontrib><creatorcontrib>Yin, Wenting</creatorcontrib><creatorcontrib>Yin, Jun</creatorcontrib><creatorcontrib>Xu, Zhaochao</creatorcontrib><title>A naphthalimide-based fluorescent sensor for halogenated solvents</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A fluorescent sensor for halogenated solvents termed
AMN
is reported.
AMN
shows strong fluorescence in most halogenated solvents (QE > 0.1) but weak fluorescence (QE<0.01) in most non-halogenated solvents. In chlorinated solvents, the fluorescence intensity decreased with the reduction of chlorine content. On the contrary, in brominated solvents the fluorescence intensity increased with the reduction of bromine content. It is worth mentioning that
AMN
displayed fluorescence emission centered at 520 nm in CCl
4
with a quantum yield of 0.607, at 556 nm in CHCl
3
with a quantum yield of 0.318, at 584 nm in CH
2
Cl
2
with a quantum yield of 0.128, whereas in CHBr
3
was centered at 441 nm with a quantum yield of 0.012.
AMN
was shown to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
halogenated solvents.
AMN
is the first sensor to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
from halogenated solvents.</description><subject>Carbon tetrachloride</subject><subject>Chlorine</subject><subject>Emission</subject><subject>Fluorescence</subject><subject>Halogenated</subject><subject>Reduction</subject><subject>Sensors</subject><subject>Solvents</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqF0c9LwzAUB_AgipvTi3elRxGqL03z6ziKOmHgRcFbSdLUVdpmJq3gf2_m5jwaCAm8D4-8bxA6x3CDgchbQ40BmQNZHaApJixPaS5eDzd3KlNOcjpBJyG8Q1yYimM0yRiTWAg8RfN50qv1aliptumayqZaBVsldTs6b4Ox_ZAE2wfnkzruqNyb7dUQSXDtZyyHU3RUqzbYs905Qy_3d8_FIl0-PTwW82VqchBDyjMNkgtZawZKcGYptVazuq54lUmIc4DJqAHCNcWgKOdYZ7QCqjEmOMdkhq62fdfefYw2DGXXxAe2reqtG0OJBUAe55Lsf8oZSBCMZZFeb6nxLgRv63Ltm075rxJDuUm3LGhR_KS7iPhy13fUna329DfOCC62wAezr_59D_kGjXt9OA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Dai, Li</creator><creator>Wu, Di</creator><creator>Qiao, Qinglong</creator><creator>Yin, Wenting</creator><creator>Yin, Jun</creator><creator>Xu, Zhaochao</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>A naphthalimide-based fluorescent sensor for halogenated solvents</title><author>Dai, Li ; Wu, Di ; Qiao, Qinglong ; Yin, Wenting ; Yin, Jun ; Xu, Zhaochao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-72b09789fb60a876e55eeb6ffd7d2900390c25c037b510a5771b25d05b1131413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Carbon tetrachloride</topic><topic>Chlorine</topic><topic>Emission</topic><topic>Fluorescence</topic><topic>Halogenated</topic><topic>Reduction</topic><topic>Sensors</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Li</creatorcontrib><creatorcontrib>Wu, Di</creatorcontrib><creatorcontrib>Qiao, Qinglong</creatorcontrib><creatorcontrib>Yin, Wenting</creatorcontrib><creatorcontrib>Yin, Jun</creatorcontrib><creatorcontrib>Xu, Zhaochao</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Li</au><au>Wu, Di</au><au>Qiao, Qinglong</au><au>Yin, Wenting</au><au>Yin, Jun</au><au>Xu, Zhaochao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A naphthalimide-based fluorescent sensor for halogenated solvents</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>52</volume><issue>1</issue><spage>295</spage><epage>298</epage><pages>295-298</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A fluorescent sensor for halogenated solvents termed
AMN
is reported.
AMN
shows strong fluorescence in most halogenated solvents (QE > 0.1) but weak fluorescence (QE<0.01) in most non-halogenated solvents. In chlorinated solvents, the fluorescence intensity decreased with the reduction of chlorine content. On the contrary, in brominated solvents the fluorescence intensity increased with the reduction of bromine content. It is worth mentioning that
AMN
displayed fluorescence emission centered at 520 nm in CCl
4
with a quantum yield of 0.607, at 556 nm in CHCl
3
with a quantum yield of 0.318, at 584 nm in CH
2
Cl
2
with a quantum yield of 0.128, whereas in CHBr
3
was centered at 441 nm with a quantum yield of 0.012.
AMN
was shown to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
halogenated solvents.
AMN
is the first sensor to have the ability to differentiate CCl
4
, CHCl
3
, CH
2
Cl
2
and CHBr
3
from halogenated solvents.</abstract><cop>England</cop><pmid>26691881</pmid><doi>10.1039/c5cc09403h</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2016-01, Vol.52 (1), p.295-298 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c5cc09403h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Carbon tetrachloride Chlorine Emission Fluorescence Halogenated Reduction Sensors Solvents |
| title | A naphthalimide-based fluorescent sensor for halogenated solvents |
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