Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chloridesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cc04432d
The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction...
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| creator | Karanjit, Sangita Jinasan, Atchaleeya Samsook, Ekasith Dhital, Raghu N Motomiya, Kenichi Sato, Yoshinori Tohji, Kazuyuki Sakurai, Hidehiro |
| description | The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by
in situ
generated Au-rich bimetallic Au/Pd nanoclusters.
The stabilization of Pd by Au in Au/Pd bimetallic nanoclusters enhanced the reactivity of Pd and changed the reaction mechanism. |
| doi_str_mv | 10.1039/c5cc04432d |
| format | Article |
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in situ
generated Au-rich bimetallic Au/Pd nanoclusters.
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in situ
generated Au-rich bimetallic Au/Pd nanoclusters.
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in situ
generated Au-rich bimetallic Au/Pd nanoclusters.
The stabilization of Pd by Au in Au/Pd bimetallic nanoclusters enhanced the reactivity of Pd and changed the reaction mechanism.</abstract><doi>10.1039/c5cc04432d</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chloridesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cc04432d |
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