Platinum trimethyl bipyridyl thiolates - new, tunable, red- to near IR emitting luminophores for bioimaging applicationsElectronic supplementary information (ESI) available: Synthesis and spectroscopic and crystallographic details of new materials, further details of DFT calculations, predicted absorption/emission spectra and orbitals involved. CCDC 1045315-1045320. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc04003e
Synthetic, spectroscopic, computational and biological imaging studies of platinum trimethyl bipyridyl thiolate complexes of the general formula [PtMe 3 (bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition...
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