Platinum trimethyl bipyridyl thiolates - new, tunable, red- to near IR emitting luminophores for bioimaging applicationsElectronic supplementary information (ESI) available: Synthesis and spectroscopic and crystallographic details of new materials, further details of DFT calculations, predicted absorption/emission spectra and orbitals involved. CCDC 1045315-1045320. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc04003e
Synthetic, spectroscopic, computational and biological imaging studies of platinum trimethyl bipyridyl thiolate complexes of the general formula [PtMe 3 (bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition...
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| creator | Steel, Harriet L Allinson, Sarah L Andre, Jane Coogan, Michael P Platts, James A |
| description | Synthetic, spectroscopic, computational and biological imaging studies of platinum trimethyl bipyridyl thiolate complexes of the general formula [PtMe
3
(bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition, and in some cases emit into the Near infra-red (NIR).
[PtMe
3
(S-C
6
H
4
-4-CO
2
Me)(bpy)]
n
+
exemplifies a new class of luminophores, absorbing in the visible and emitting into the NIR, with good cell uptake making it suitable for fluorescence microscopy imaging. |
| doi_str_mv | 10.1039/c5cc04003e |
| format | Article |
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3
(bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition, and in some cases emit into the Near infra-red (NIR).
[PtMe
3
(S-C
6
H
4
-4-CO
2
Me)(bpy)]
n
+
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3
(bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition, and in some cases emit into the Near infra-red (NIR).
[PtMe
3
(S-C
6
H
4
-4-CO
2
Me)(bpy)]
n
+
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3
(bpy)SR] reveal these to be easily accessed, tunable bioimaging agents which feature an unusual σ-π* Inter-Ligand Charge Transfer (ILCT) transition, and in some cases emit into the Near infra-red (NIR).
[PtMe
3
(S-C
6
H
4
-4-CO
2
Me)(bpy)]
n
+
exemplifies a new class of luminophores, absorbing in the visible and emitting into the NIR, with good cell uptake making it suitable for fluorescence microscopy imaging.</abstract><doi>10.1039/c5cc04003e</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Platinum trimethyl bipyridyl thiolates - new, tunable, red- to near IR emitting luminophores for bioimaging applicationsElectronic supplementary information (ESI) available: Synthesis and spectroscopic and crystallographic details of new materials, further details of DFT calculations, predicted absorption/emission spectra and orbitals involved. CCDC 1045315-1045320. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc04003e |
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