Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j

The addition of CO to [((R 3 N)BH 2 ) 2 (μ-H)][B(C 6 F 5 ) 4 ] leads to formation of trimethylboroxine ((MeBO) 3 ) and [(R 3 N) 2 BH 2 ][B(C 6 F 5 ) 4 ]. When R = Et, [(Et 3 N)H 2 B(μ-O)B(CH 3 )NEt 3 ][B(C 6 F 5 ) 4 ], is isolated and demonstrated to be an intermediate in the formation of (MeBO) 3 ....

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Hauptverfasser:	Curless, Liam D, Clark, Ewan R, Cid, Jessica, Del Grosso, Alessandro, Ingleson, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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