Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j
The addition of CO to [((R 3 N)BH 2 ) 2 (μ-H)][B(C 6 F 5 ) 4 ] leads to formation of trimethylboroxine ((MeBO) 3 ) and [(R 3 N) 2 BH 2 ][B(C 6 F 5 ) 4 ]. When R = Et, [(Et 3 N)H 2 B(μ-O)B(CH 3 )NEt 3 ][B(C 6 F 5 ) 4 ], is isolated and demonstrated to be an intermediate in the formation of (MeBO) 3 ....
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| creator | Curless, Liam D Clark, Ewan R Cid, Jessica Del Grosso, Alessandro Ingleson, Michael J |
| description | The addition of CO to [((R
3
N)BH
2
)
2
(μ-H)][B(C
6
F
5
)
4
] leads to formation of trimethylboroxine ((MeBO)
3
) and [(R
3
N)
2
BH
2
][B(C
6
F
5
)
4
]. When R = Et, [(Et
3
N)H
2
B(μ-O)B(CH
3
)NEt
3
][B(C
6
F
5
)
4
], is isolated and demonstrated to be an intermediate in the formation of (MeBO)
3
.
CO undergoes complete reductive cleavage using highly electrophilic hydride bridged borocations to ultimately yield trimethylboroxine and the boronium salt. |
| doi_str_mv | 10.1039/c5cc03504j |
| format | Article |
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3
N)BH
2
)
2
(μ-H)][B(C
6
F
5
)
4
] leads to formation of trimethylboroxine ((MeBO)
3
) and [(R
3
N)
2
BH
2
][B(C
6
F
5
)
4
]. When R = Et, [(Et
3
N)H
2
B(μ-O)B(CH
3
)NEt
3
][B(C
6
F
5
)
4
], is isolated and demonstrated to be an intermediate in the formation of (MeBO)
3
.
CO undergoes complete reductive cleavage using highly electrophilic hydride bridged borocations to ultimately yield trimethylboroxine and the boronium salt.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc03504j</identifier><language>eng</language><creationdate>2015-06</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Curless, Liam D</creatorcontrib><creatorcontrib>Clark, Ewan R</creatorcontrib><creatorcontrib>Cid, Jessica</creatorcontrib><creatorcontrib>Del Grosso, Alessandro</creatorcontrib><creatorcontrib>Ingleson, Michael J</creatorcontrib><title>Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j</title><description>The addition of CO to [((R
3
N)BH
2
)
2
(μ-H)][B(C
6
F
5
)
4
] leads to formation of trimethylboroxine ((MeBO)
3
) and [(R
3
N)
2
BH
2
][B(C
6
F
5
)
4
]. When R = Et, [(Et
3
N)H
2
B(μ-O)B(CH
3
)NEt
3
][B(C
6
F
5
)
4
], is isolated and demonstrated to be an intermediate in the formation of (MeBO)
3
.
CO undergoes complete reductive cleavage using highly electrophilic hydride bridged borocations to ultimately yield trimethylboroxine and the boronium salt.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkb1PwzAQxQMCic-FHenYQGpLoiQ07ZqmogNUAga24jqXxpUbW7Zbkf-eSwJiQIAXn_x-vnvP9ryLwB8Efji65THnfhj70XrfOw7Cu6gfR8nrQVPHo_4wjOIj78TatU8riJPjvbdUbbREh2Aw33IndghcItuxFYIqIJ1DwbiQwjGHOSxrKMWqlDWgRO6M0iVpHJbKKM6cUJXNOqGiU7vV1HuDlWOmBlEVymxaCK6z59kN0BQh2VLiGLJ3jUa0qARNzciNQdsDTv7UtsqBl8ww7oiyXY-cOdaDx4cnsLoZyYA1mKkt9ZBqZRiZ4y02gDSdpBD4cTJMwpbr6mgAU2WA3Px-mYxDOpsCccqVaL6iNwm7RGARYTKfjeHnP5x5hwWTFs8_91Pvcpq9pPd9Y_lCU2R6msU3Hv6vX_2lL3RehB8FWKoT</recordid><startdate>20150623</startdate><enddate>20150623</enddate><creator>Curless, Liam D</creator><creator>Clark, Ewan R</creator><creator>Cid, Jessica</creator><creator>Del Grosso, Alessandro</creator><creator>Ingleson, Michael J</creator><scope/></search><sort><creationdate>20150623</creationdate><title>Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j</title><author>Curless, Liam D ; Clark, Ewan R ; Cid, Jessica ; Del Grosso, Alessandro ; Ingleson, Michael J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5cc03504j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Curless, Liam D</creatorcontrib><creatorcontrib>Clark, Ewan R</creatorcontrib><creatorcontrib>Cid, Jessica</creatorcontrib><creatorcontrib>Del Grosso, Alessandro</creatorcontrib><creatorcontrib>Ingleson, Michael J</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Curless, Liam D</au><au>Clark, Ewan R</au><au>Cid, Jessica</au><au>Del Grosso, Alessandro</au><au>Ingleson, Michael J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j</atitle><date>2015-06-23</date><risdate>2015</risdate><volume>51</volume><issue>54</issue><spage>193</spage><epage>196</epage><pages>193-196</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The addition of CO to [((R
3
N)BH
2
)
2
(μ-H)][B(C
6
F
5
)
4
] leads to formation of trimethylboroxine ((MeBO)
3
) and [(R
3
N)
2
BH
2
][B(C
6
F
5
)
4
]. When R = Et, [(Et
3
N)H
2
B(μ-O)B(CH
3
)NEt
3
][B(C
6
F
5
)
4
], is isolated and demonstrated to be an intermediate in the formation of (MeBO)
3
.
CO undergoes complete reductive cleavage using highly electrophilic hydride bridged borocations to ultimately yield trimethylboroxine and the boronium salt.</abstract><doi>10.1039/c5cc03504j</doi><tpages>4</tpages></addata></record> |
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| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Complete reductive cleavage of CO facilitated by highly electrophilic borocationsElectronic supplementary information (ESI) available: Experimental procedures, compound characterisation data, NMR spectra and crystallographic data. CCDC 1058783 and 1058784. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc03504j |
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