Titanium migration driven by Li vacancies in Li1−xTi2O4 spinelElectronic supplementary information (ESI) available: Cif file for the combined PXRD and PND refinement of Li0.33Ti2O4. See DOI: 10.1039/c5cc02800k
Gentle oxidation of lithium titanate spinel (LiTi 2 O 4 ) with water at room temperature gives Li-deficient Li 0.33 Ti 2 O 4 . Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-mig...
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| creator | Kitada, A Arevalo-Lopez, A. M Attfield, J. P |
| description | Gentle oxidation of lithium titanate spinel (LiTi
2
O
4
) with water at room temperature gives Li-deficient Li
0.33
Ti
2
O
4
. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
Gentle oxidation of lithium titanate by water gives Li
0.33
Ti
2
O
4
with many Ti cations displaced to alternative octahedral sites (marked 'X'). |
| doi_str_mv | 10.1039/c5cc02800k |
| format | Article |
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2
O
4
) with water at room temperature gives Li-deficient Li
0.33
Ti
2
O
4
. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
Gentle oxidation of lithium titanate by water gives Li
0.33
Ti
2
O
4
with many Ti cations displaced to alternative octahedral sites (marked 'X').</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc02800k</identifier><language>eng</language><creationdate>2015-07</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Kitada, A</creatorcontrib><creatorcontrib>Arevalo-Lopez, A. M</creatorcontrib><creatorcontrib>Attfield, J. P</creatorcontrib><title>Titanium migration driven by Li vacancies in Li1−xTi2O4 spinelElectronic supplementary information (ESI) available: Cif file for the combined PXRD and PND refinement of Li0.33Ti2O4. See DOI: 10.1039/c5cc02800k</title><description>Gentle oxidation of lithium titanate spinel (LiTi
2
O
4
) with water at room temperature gives Li-deficient Li
0.33
Ti
2
O
4
. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
Gentle oxidation of lithium titanate by water gives Li
0.33
Ti
2
O
4
with many Ti cations displaced to alternative octahedral sites (marked 'X').</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFT01PAjEQbYwm4sfFu8l40wNrl-7qwhUwkhgxwoEbKWWqo2130y4E_oFn_5r_wF9iURMPJjqXeTPv5b0Zxo5SnqRctM9VrhRvFZw_b7FGKi6yZp4Vk-0NztvNS5Hlu2wvhCceK82LBnsbUy0dLSxYevCyptLB3NMSHczWcEOwlEo6RRiAXJzT95fX1ZhawwxCRQ5N36CqfelIQVhUlUGLrpZ-HeW69PbL8bQ_GpyBXEoycmawA13SoMkgRA3UjwiqtLNoN4e7yX0PpIvgtgcedVxuHKHUMZ0nQnyGJzBChN5w0IHfrx-wHS1NwMPvvs-Or_rj7nXTBzWtPNl43vRHLv7nT_7ip9Vciw_DEnb0</recordid><startdate>20150702</startdate><enddate>20150702</enddate><creator>Kitada, A</creator><creator>Arevalo-Lopez, A. M</creator><creator>Attfield, J. P</creator><scope/></search><sort><creationdate>20150702</creationdate><title>Titanium migration driven by Li vacancies in Li1−xTi2O4 spinelElectronic supplementary information (ESI) available: Cif file for the combined PXRD and PND refinement of Li0.33Ti2O4. See DOI: 10.1039/c5cc02800k</title><author>Kitada, A ; Arevalo-Lopez, A. M ; Attfield, J. P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5cc02800k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kitada, A</creatorcontrib><creatorcontrib>Arevalo-Lopez, A. M</creatorcontrib><creatorcontrib>Attfield, J. P</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kitada, A</au><au>Arevalo-Lopez, A. M</au><au>Attfield, J. P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Titanium migration driven by Li vacancies in Li1−xTi2O4 spinelElectronic supplementary information (ESI) available: Cif file for the combined PXRD and PND refinement of Li0.33Ti2O4. See DOI: 10.1039/c5cc02800k</atitle><date>2015-07-02</date><risdate>2015</risdate><volume>51</volume><issue>57</issue><spage>11359</spage><epage>11361</epage><pages>11359-11361</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Gentle oxidation of lithium titanate spinel (LiTi
2
O
4
) with water at room temperature gives Li-deficient Li
0.33
Ti
2
O
4
. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
Gentle oxidation of lithium titanate by water gives Li
0.33
Ti
2
O
4
with many Ti cations displaced to alternative octahedral sites (marked 'X').</abstract><doi>10.1039/c5cc02800k</doi><tpages>3</tpages></addata></record> |
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| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c5cc02800k |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Titanium migration driven by Li vacancies in Li1−xTi2O4 spinelElectronic supplementary information (ESI) available: Cif file for the combined PXRD and PND refinement of Li0.33Ti2O4. See DOI: 10.1039/c5cc02800k |
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