Experimental and mechanistic analysis of the palladium-catalyzed oxidative C8-selective C-H homocoupling of quinoline N-oxidesElectronic supplementary information (ESI) available: Experimental procedures and characterization data. CCDC 1037965. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc02227d

Experimental and mechanistic analysis of the palladium-catalyzed oxidative C8-selective C-H homocoupling of quinoline N-oxidesElectronic supplementary information (ESI) available: Experimental procedures and characterization data. CCDC 1037965. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc02227d

A novel site-selective palladium-catalyzed oxidative C8-H homocoupling reaction of quinoline N -oxides has been developed. The reaction affords substituted 8,8′-biquinolyl N,N ′-dioxides that can be readily converted to a variety of functionalized 8,8′-biquinolyls. Mechanistic studies point to the c...

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Hauptverfasser: Stephens, David E, Lakey-Beitia, Johant, Chavez, Gabriel, Ilie, Carla, Arman, Hadi D, Larionov, Oleg V
Format: Artikel
Sprache:eng
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