Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenesElectronic supplementary information (ESI) available: Experimental details of the synthesis method of chiral 1, CD and UV-vis spectra of possible eleven conformers and their CD/UV-vis spectra. See DOI: 10.1039/c5cc01465d

2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals. This cryptochirality was deciphered in the photoexcited state by circularly polarised lumine...

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Hauptverfasser: Amako, Tomoyuki, Nakabayashi, Kazuki, Suzuki, Nozomu, Guo, Sibo, Rahim, Nor Azura Abdul, Harada, Takunori, Fujiki, Michiya, Imai, Yoshitane
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Sprache:eng
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Zusammenfassung:2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals. This cryptochirality was deciphered in the photoexcited state by circularly polarised luminescence signals. 2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01465d