Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcoholsElectronic supplementary information (ESI) available: Experimental procedures and electrochemical data. See DOI: 10.1039/c5cc01107h
Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s −1 . These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be...
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| creator | Weiss, Charles J Wiedner, Eric S Roberts, John A. S Appel, Aaron M |
| description | Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s
−1
. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
Nickel phosphine complexes with pendant amines are reported as the first nonprecious metal molecular electrocatalysts for the oxidation of alcohols. |
| doi_str_mv | 10.1039/c5cc01107h |
| format | Article |
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−1
. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
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−1
. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
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−1
. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcoholsElectronic supplementary information (ESI) available: Experimental procedures and electrochemical data. See DOI: 10.1039/c5cc01107h |
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