Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groupsElectronic supplementary information (ESI) available: Experimental procedures, characterization data of compounds, NMR spectra and HRMS spectra of new compounds. See DOI: 10.1039/c5cc00430f
A highly efficient palladium-catalyzed acylative cross-coupling of carboxylic amides with arylboronic acids has been achieved via synergistic activation of the C acyl -N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also...
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creator | Li, Xijing Zou, Gang |
description | A highly efficient palladium-catalyzed acylative cross-coupling of carboxylic amides with arylboronic acids has been achieved
via
synergistic activation of the C
acyl
-N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also modifiable reactivities to overcome steric hindrance.
Highly efficient Pd/PCy
3
-catalyzed acylative Suzuki coupling of carboxylic amides has been achieved to provide a variety of aryl ketones, including sterically hindered thus difficultly accessible ones. |
doi_str_mv | 10.1039/c5cc00430f |
format | Article |
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via
synergistic activation of the C
acyl
-N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also modifiable reactivities to overcome steric hindrance.
Highly efficient Pd/PCy
3
-catalyzed acylative Suzuki coupling of carboxylic amides has been achieved to provide a variety of aryl ketones, including sterically hindered thus difficultly accessible ones.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc00430f</identifier><language>eng</language><creationdate>2015-03</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Xijing</creatorcontrib><creatorcontrib>Zou, Gang</creatorcontrib><title>Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groupsElectronic supplementary information (ESI) available: Experimental procedures, characterization data of compounds, NMR spectra and HRMS spectra of new compounds. See DOI: 10.1039/c5cc00430f</title><description>A highly efficient palladium-catalyzed acylative cross-coupling of carboxylic amides with arylboronic acids has been achieved
via
synergistic activation of the C
acyl
-N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also modifiable reactivities to overcome steric hindrance.
Highly efficient Pd/PCy
3
-catalyzed acylative Suzuki coupling of carboxylic amides has been achieved to provide a variety of aryl ketones, including sterically hindered thus difficultly accessible ones.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkL1PwzAQxQMCifKxsCMdG0ikJEoCbTcEQe1QkBoGtso4l2BwbMtOCulfz4WidkACD_6633vvbM87DoN-GETDS55wHgRxFBTbXi-MrmI_iQfPO90-GfrXUZzsefvOvQU0wmTQ24pveCtZLRYIWbNs3gVw3RgpVAm6AFaJHN0IGEG-ErXVJSo6EU8arWAhGLhWoS3bjhcqR4M0qVq2UOlcFIK9SFxLyLa0FOBSiZzslODgGmMkVqRhtiWLQttq5X6WZpNzYAsmZOcygvTToBXfqARjNce8segugL8ySxlUXK6kOatZ1xHXldGNyol5mM7AmS6WAVM5jGfTbH1BqMKPDd6HDBHuHicj-P23h95uwaTDo5_1wDu5T59ux751fG6oQXrIfINH_9dP_6rPTV5EX3lgngE</recordid><startdate>20150310</startdate><enddate>20150310</enddate><creator>Li, Xijing</creator><creator>Zou, Gang</creator><scope/></search><sort><creationdate>20150310</creationdate><title>Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groupsElectronic supplementary information (ESI) available: Experimental procedures, characterization data of compounds, NMR spectra and HRMS spectra of new compounds. See DOI: 10.1039/c5cc00430f</title><author>Li, Xijing ; Zou, Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c5cc00430f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Xijing</creatorcontrib><creatorcontrib>Zou, Gang</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xijing</au><au>Zou, Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groupsElectronic supplementary information (ESI) available: Experimental procedures, characterization data of compounds, NMR spectra and HRMS spectra of new compounds. See DOI: 10.1039/c5cc00430f</atitle><date>2015-03-10</date><risdate>2015</risdate><volume>51</volume><issue>24</issue><spage>589</spage><epage>592</epage><pages>589-592</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A highly efficient palladium-catalyzed acylative cross-coupling of carboxylic amides with arylboronic acids has been achieved
via
synergistic activation of the C
acyl
-N bond by independently modifiable activating groups. Coupling of amides features not only good functional group tolerance but also modifiable reactivities to overcome steric hindrance.
Highly efficient Pd/PCy
3
-catalyzed acylative Suzuki coupling of carboxylic amides has been achieved to provide a variety of aryl ketones, including sterically hindered thus difficultly accessible ones.</abstract><doi>10.1039/c5cc00430f</doi><tpages>4</tpages></addata></record> |
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title | Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groupsElectronic supplementary information (ESI) available: Experimental procedures, characterization data of compounds, NMR spectra and HRMS spectra of new compounds. See DOI: 10.1039/c5cc00430f |
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