Synthesis of model humic substances: a mechanistic study using controllable H/D exchange and Fourier transform ion cyclotron resonance mass spectrometryElectronic supplementary information (ESI) available: (1) Synthetic protocols for the intermediate reagents used for synthesis of the phenylpropanoic monomer; (2) 1H NMR spectra of the synthetic products; (3) reaction pathways leading to the formation of the products from 9 to 11; (4) mass lists with errors of identifications and the correspondin
The products of the oxidative coupling of phenols are frequently used as synthetic analogues to natural humic substances (HS) for biomedical research. However, their molecular compositions and exact structures remain largely unknown. The objective of this study was to develop a novel approach for th...
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