The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells

Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurement...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (17), p.9165-917
Hauptverfasser: Zhang, Lijun, Liu, Tongfa, Liu, Linfeng, Hu, Min, Yang, Ying, Mei, Anyi, Han, Hongwei
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container_issue 17
container_start_page 9165
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 3
creator Zhang, Lijun
Liu, Tongfa
Liu, Linfeng
Hu, Min
Yang, Ying
Mei, Anyi
Han, Hongwei
description Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurements were carried out to study the influence of CEs on the photovoltaic performance of devices. The results indicated that graphite, which acted as the conductor in carbon counter electrodes (CCEs), could significantly affect the square resistance of CCEs, thus resulting in differences in fill factor and power conversion efficiency (PCE) of the devices. Based on the optimized CCEs with a thickness of 9 μm, PCEs exceeding 11% could be achieved for the fully printable hole-conductor-free mesoscopic perovskite solar cells due to the low square resistance and large pore size of graphite based CCEs. The abundant availability, low cost and excellent properties of such carbon material based CEs offer a wide prospect for their further applications in perovskite solar cells. The size effect of graphite on hole-conductor-free fully printable mesoscopic perovskite solar cells was studied.
doi_str_mv 10.1039/c4ta04647a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Carbon
Devices
Electrodes
Energy conversion efficiency
Graphite
Perovskites
Photovoltaic cells
Solar cells
title The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells
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