The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells
Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurement...
Gespeichert in:
Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (17), p.9165-917 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 917 |
---|---|
container_issue | 17 |
container_start_page | 9165 |
container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
container_volume | 3 |
creator | Zhang, Lijun Liu, Tongfa Liu, Linfeng Hu, Min Yang, Ying Mei, Anyi Han, Hongwei |
description | Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurements were carried out to study the influence of CEs on the photovoltaic performance of devices. The results indicated that graphite, which acted as the conductor in carbon counter electrodes (CCEs), could significantly affect the square resistance of CCEs, thus resulting in differences in fill factor and power conversion efficiency (PCE) of the devices. Based on the optimized CCEs with a thickness of 9 μm, PCEs exceeding 11% could be achieved for the fully printable hole-conductor-free mesoscopic perovskite solar cells due to the low square resistance and large pore size of graphite based CCEs. The abundant availability, low cost and excellent properties of such carbon material based CEs offer a wide prospect for their further applications in perovskite solar cells.
The size effect of graphite on hole-conductor-free fully printable mesoscopic perovskite solar cells was studied. |
doi_str_mv | 10.1039/c4ta04647a |
format | Article |
fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c4ta04647a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1680451338</sourcerecordid><originalsourceid>FETCH-LOGICAL-c452t-2d95e53611ab7c4b3109f8b52feacd4fbb2854ca41b4893d5602af02962ba2ea3</originalsourceid><addsrcrecordid>eNqNkU1LAzEQhoMoWGov3oV4E2E1n7vJsRS_QPBSb8KSZCe4mjZrsiv037u1Um_iXGZ452GYeQehU0quKOH62oneEFGKyhygCSOSFJXQ5eG-VuoYzXJ-I2MoQkqtJ-hl-QoYvAfX4-ixM8nGNXZxWPeQMIRRT7GBjEfVDyFscJfadW9sALyCHLOLXetwByl-5ve2B5xjMAk7CCGfoCNvQobZT56i59ub5eK-eHy6e1jMHwsnJOsL1mgJkpeUGls5YTkl2isrmQfjGuGtZUoKZwS1QmneyJIw4wnTJbOGgeFTdLGb26X4MUDu61WbtxuYNcQh17RUstKqZOI_KBGScq5G9HKHuhRzTuDr8fSVSZuaknpreL0Qy_m34fMRPtvBKbs99_uQsX_-V7_uGs-_AFsdiQk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1680451338</pqid></control><display><type>article</type><title>The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Zhang, Lijun ; Liu, Tongfa ; Liu, Linfeng ; Hu, Min ; Yang, Ying ; Mei, Anyi ; Han, Hongwei</creator><creatorcontrib>Zhang, Lijun ; Liu, Tongfa ; Liu, Linfeng ; Hu, Min ; Yang, Ying ; Mei, Anyi ; Han, Hongwei</creatorcontrib><description>Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurements were carried out to study the influence of CEs on the photovoltaic performance of devices. The results indicated that graphite, which acted as the conductor in carbon counter electrodes (CCEs), could significantly affect the square resistance of CCEs, thus resulting in differences in fill factor and power conversion efficiency (PCE) of the devices. Based on the optimized CCEs with a thickness of 9 μm, PCEs exceeding 11% could be achieved for the fully printable hole-conductor-free mesoscopic perovskite solar cells due to the low square resistance and large pore size of graphite based CCEs. The abundant availability, low cost and excellent properties of such carbon material based CEs offer a wide prospect for their further applications in perovskite solar cells.
The size effect of graphite on hole-conductor-free fully printable mesoscopic perovskite solar cells was studied.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c4ta04647a</identifier><language>eng</language><subject>Carbon ; Devices ; Electrodes ; Energy conversion efficiency ; Graphite ; Perovskites ; Photovoltaic cells ; Solar cells</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2015-01, Vol.3 (17), p.9165-917</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-2d95e53611ab7c4b3109f8b52feacd4fbb2854ca41b4893d5602af02962ba2ea3</citedby><cites>FETCH-LOGICAL-c452t-2d95e53611ab7c4b3109f8b52feacd4fbb2854ca41b4893d5602af02962ba2ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Zhang, Lijun</creatorcontrib><creatorcontrib>Liu, Tongfa</creatorcontrib><creatorcontrib>Liu, Linfeng</creatorcontrib><creatorcontrib>Hu, Min</creatorcontrib><creatorcontrib>Yang, Ying</creatorcontrib><creatorcontrib>Mei, Anyi</creatorcontrib><creatorcontrib>Han, Hongwei</creatorcontrib><title>The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurements were carried out to study the influence of CEs on the photovoltaic performance of devices. The results indicated that graphite, which acted as the conductor in carbon counter electrodes (CCEs), could significantly affect the square resistance of CCEs, thus resulting in differences in fill factor and power conversion efficiency (PCE) of the devices. Based on the optimized CCEs with a thickness of 9 μm, PCEs exceeding 11% could be achieved for the fully printable hole-conductor-free mesoscopic perovskite solar cells due to the low square resistance and large pore size of graphite based CCEs. The abundant availability, low cost and excellent properties of such carbon material based CEs offer a wide prospect for their further applications in perovskite solar cells.
The size effect of graphite on hole-conductor-free fully printable mesoscopic perovskite solar cells was studied.</description><subject>Carbon</subject><subject>Devices</subject><subject>Electrodes</subject><subject>Energy conversion efficiency</subject><subject>Graphite</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkU1LAzEQhoMoWGov3oV4E2E1n7vJsRS_QPBSb8KSZCe4mjZrsiv037u1Um_iXGZ452GYeQehU0quKOH62oneEFGKyhygCSOSFJXQ5eG-VuoYzXJ-I2MoQkqtJ-hl-QoYvAfX4-ixM8nGNXZxWPeQMIRRT7GBjEfVDyFscJfadW9sALyCHLOLXetwByl-5ve2B5xjMAk7CCGfoCNvQobZT56i59ub5eK-eHy6e1jMHwsnJOsL1mgJkpeUGls5YTkl2isrmQfjGuGtZUoKZwS1QmneyJIw4wnTJbOGgeFTdLGb26X4MUDu61WbtxuYNcQh17RUstKqZOI_KBGScq5G9HKHuhRzTuDr8fSVSZuaknpreL0Qy_m34fMRPtvBKbs99_uQsX_-V7_uGs-_AFsdiQk</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Zhang, Lijun</creator><creator>Liu, Tongfa</creator><creator>Liu, Linfeng</creator><creator>Hu, Min</creator><creator>Yang, Ying</creator><creator>Mei, Anyi</creator><creator>Han, Hongwei</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7U6</scope><scope>C1K</scope><scope>7SP</scope><scope>7SR</scope><scope>7SU</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150101</creationdate><title>The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells</title><author>Zhang, Lijun ; Liu, Tongfa ; Liu, Linfeng ; Hu, Min ; Yang, Ying ; Mei, Anyi ; Han, Hongwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-2d95e53611ab7c4b3109f8b52feacd4fbb2854ca41b4893d5602af02962ba2ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Carbon</topic><topic>Devices</topic><topic>Electrodes</topic><topic>Energy conversion efficiency</topic><topic>Graphite</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Lijun</creatorcontrib><creatorcontrib>Liu, Tongfa</creatorcontrib><creatorcontrib>Liu, Linfeng</creatorcontrib><creatorcontrib>Hu, Min</creatorcontrib><creatorcontrib>Yang, Ying</creatorcontrib><creatorcontrib>Mei, Anyi</creatorcontrib><creatorcontrib>Han, Hongwei</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Lijun</au><au>Liu, Tongfa</au><au>Liu, Linfeng</au><au>Hu, Min</au><au>Yang, Ying</au><au>Mei, Anyi</au><au>Han, Hongwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>3</volume><issue>17</issue><spage>9165</spage><epage>917</epage><pages>9165-917</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Mesoporous graphite/carbon black counter electrodes (CEs) using flaky graphite with different sizes were applied in hole-conductor-free mesoscopic perovskite solar cells by a screen-printing technique. Conductivity measurements, current-voltage characteristics, and impedance spectroscopy measurements were carried out to study the influence of CEs on the photovoltaic performance of devices. The results indicated that graphite, which acted as the conductor in carbon counter electrodes (CCEs), could significantly affect the square resistance of CCEs, thus resulting in differences in fill factor and power conversion efficiency (PCE) of the devices. Based on the optimized CCEs with a thickness of 9 μm, PCEs exceeding 11% could be achieved for the fully printable hole-conductor-free mesoscopic perovskite solar cells due to the low square resistance and large pore size of graphite based CCEs. The abundant availability, low cost and excellent properties of such carbon material based CEs offer a wide prospect for their further applications in perovskite solar cells.
The size effect of graphite on hole-conductor-free fully printable mesoscopic perovskite solar cells was studied.</abstract><doi>10.1039/c4ta04647a</doi><tpages>6</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 2050-7488 |
ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2015-01, Vol.3 (17), p.9165-917 |
issn | 2050-7488 2050-7496 |
language | eng |
recordid | cdi_rsc_primary_c4ta04647a |
source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Carbon Devices Electrodes Energy conversion efficiency Graphite Perovskites Photovoltaic cells Solar cells |
title | The effect of carbon counter electrodes on fully printable mesoscopic perovskite solar cells |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T19%3A49%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20effect%20of%20carbon%20counter%20electrodes%20on%20fully%20printable%20mesoscopic%20perovskite%20solar%20cells&rft.jtitle=Journal%20of%20materials%20chemistry.%20A,%20Materials%20for%20energy%20and%20sustainability&rft.au=Zhang,%20Lijun&rft.date=2015-01-01&rft.volume=3&rft.issue=17&rft.spage=9165&rft.epage=917&rft.pages=9165-917&rft.issn=2050-7488&rft.eissn=2050-7496&rft_id=info:doi/10.1039/c4ta04647a&rft_dat=%3Cproquest_rsc_p%3E1680451338%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1680451338&rft_id=info:pmid/&rfr_iscdi=true |