Role of 4,4′-bipyridine versus longer spacers 4,4′-azobipyridine, 1,2-bis(4-pyridyl)ethylene, and 1,2-bis(pyridin-3-ylmethylene)hydrazine in the formation of thermally labile metallophosphate coordination polymersElectronic supplementary information (ESI) available: Selected bond lengths and angles in tables and figures for 1-5 and 9-11. CCDC 942679-942683 and 1015310-1015312. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4qi00149d

One dimensional metallophosphate coordination polymers {[M(dtbp) 2 (azopy)(H 2 O) 2 ]·(azopy)} x (M = Mn ( 1 ); Co ( 2 ); Cu ( 3 ); Cd ( 4 )) have been synthesized from the reaction of a suitable metal precursor with di- tert -butylphosphate (dtbp-H) in the presence of ditopic linker 4,4′-azobipyrid...

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Hauptverfasser:	Rajakannu, Palanisamy, Howlader, Rana, Kalita, Alok Ch, Butcher, Raymond J, Murugavel, Ramaswamy
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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