Hydrophobe-free miniemulsion polymerization: towards high solid content of fatty acid-based poly(urethane-urea) latexesElectronic supplementary information (ESI) available: Experimental data, protocols, NMR spectra of monomers and polymers, SEC spectra and DSC thermograms of polymers. See DOI: 10.1039/c4py00960f
Polyurethane-urea latex particles were synthesized by miniemulsion polyaddition of fatty acid-based diol derivatives and isophorone diisocyanate. The influence of the solid content, the surfactant and the hydrophobic agent was studied. Stable monodispersed latex particles with diameters around 200-3...
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