One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; functionalisation to homoallylic boronate carboxylate ester derivativesElectronic supplementary information (ESI) available: Further experimental details, ReactIR spectra, all 1H, 13C and 11B NMRs, and X-ray crystallographic details. CCDC 1040392 (2a), 1040393 (2b), 1040394 (2e), 1040395 (2h) and 1040594 (2j). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02657h

The β-borylation reaction of α,β-unsaturated aldehyde-derived imines, formed in situ , has been studied using a one-pot methodology, as a route to β-boryl aldehydes. The instability of the β-boryl aldehydes meant that derivatisation was required and routes to both acetal derivatives and homoallylic...

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Hauptverfasser:	Pujol, Alba, Calow, Adam D. J, Batsanov, Andrei S, Whiting, Andrew
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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