Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysisElectronic supplementary information (ESI) available: Experimental procedures and data, NMR spectra and X-ray data for 12c. CCDC 1017544. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02056a
Versatile syntheses of C2-linked and C 2 -symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl] 2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promisin...
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| creator | Henderson, Alexander S Bower, John F Galan, M. Carmen |
| description | Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]
2
and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.
Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones. |
| doi_str_mv | 10.1039/c4ob02056a |
| format | Article |
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C
2
-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]
2
and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.
Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/c4ob02056a</identifier><language>eng</language><creationdate>2014-10</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Henderson, Alexander S</creatorcontrib><creatorcontrib>Bower, John F</creatorcontrib><creatorcontrib>Galan, M. Carmen</creatorcontrib><title>Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysisElectronic supplementary information (ESI) available: Experimental procedures and data, NMR spectra and X-ray data for 12c. CCDC 1017544. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02056a</title><description>Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]
2
and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.
Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones.</description><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUDtPwzAQDggkngs70rGBRIrzaKt2TVPRgSIBA1t1ca7EyLUjO63Iv-caEB2QYLL1ve67C4KLSPQikYzuZGoLEYv-APeD4ygdDkPRT0YHP_9YHAUn3r8LEY2Gg_R4L87QFbZqS4cNhQV6KmEeVtSQs7KVWkmQrCBDHpbWARk0jbKeNMlGbYjZBnXrlc-3iLOGHX5d15pWZBp0LSjDxhWyy8B1_jy7Adyg0lhoGkP-UZNTnVRDzTOpXDuehaaEkqNvYf7wBL7eZmOHvoYO247rCkWx7EGWTTKIRDTsp2kPpgzznE4tXes5Wts3h3XF3TqjMpDNpsA621TEW-26f3UFTwSTx9kYfl_2LDhcovZ0_v2eBpfT_CW7D52Xi5qX4aUXO3nyP3_1F7-oy2XyCaqymKA</recordid><startdate>20141029</startdate><enddate>20141029</enddate><creator>Henderson, Alexander S</creator><creator>Bower, John F</creator><creator>Galan, M. Carmen</creator><scope/></search><sort><creationdate>20141029</creationdate><title>Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysisElectronic supplementary information (ESI) available: Experimental procedures and data, NMR spectra and X-ray data for 12c. CCDC 1017544. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02056a</title><author>Henderson, Alexander S ; Bower, John F ; Galan, M. Carmen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c4ob02056a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Henderson, Alexander S</creatorcontrib><creatorcontrib>Bower, John F</creatorcontrib><creatorcontrib>Galan, M. Carmen</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Henderson, Alexander S</au><au>Bower, John F</au><au>Galan, M. Carmen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysisElectronic supplementary information (ESI) available: Experimental procedures and data, NMR spectra and X-ray data for 12c. CCDC 1017544. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02056a</atitle><date>2014-10-29</date><risdate>2014</risdate><volume>12</volume><issue>45</issue><spage>918</spage><epage>9183</epage><pages>918-9183</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]
2
and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.
Versatile syntheses of C2-linked and
C
2
-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones.</abstract><doi>10.1039/c4ob02056a</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysisElectronic supplementary information (ESI) available: Experimental procedures and data, NMR spectra and X-ray data for 12c. CCDC 1017544. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob02056a |
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