A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenonesElectronic supplementary information (ESI) available: Representation of the NICS, gif movies and the Cartesian coordinates for all the species described in the text. See DOI: 10.1039/c4ob00562g

A new mechanism for the rearrangement of vinyl allene oxide geometric isomers to stereodefined cyclopentenones is proposed based on DFT computations. This mechanism comprises two steps, first the ring opening of the oxirane to give a vinylcyclopropanone, and then a [1,3]-C sigmatropic rearrangement....

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Hauptverfasser:	González-Pérez, Adán B, Grechkin, Alexander, de Lera, Ángel R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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