Solvent-free synthesis of Cu2ZnSnS4 nanocrystals: a facile, green, up-scalable route for low cost photovoltaic cellsElectronic supplementary information (ESI) available: XPS spectra of the as-synthesized CZTS NCs, XRD, Raman, and XPS spectra of the CZTSe NCs right after the synthesis and after being stored for one year, the detailed procedure used to evaluate the device parameters, and TEM cross-sections of the CZTSe solar cell. See DOI: 10.1039/c4nr02564d
Efficient Cu 2 ZnSnSe 4 (CZTSe) solar cells were fabricated with a simple, environmentally friendly, and scalable synthetic method for Cu 2 ZnSnS 4 (CZTS) nanocrystals. CZTS nanoparticles were mechanochemically synthesized from elemental precursors on a relatively large scale (∼20 g), during which n...
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