Generation of graphene quantum dots by the oxidative cleavage of graphene oxide using the oxone oxidantElectronic supplementary information (ESI) available. See DOI: 10.1039/c4nj02299h
A novel and facile method to synthesize graphene quantum dots (GQDs) from graphene oxide (GO) via sonication or UV-irradiation reaction using an acid-free oxone oxidant (potassium monopersulfate) that does not require a neutralization process with a strong base was developed. Our novel sono- and pho...
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creator | Shin, Yonghun Park, Jintaek Hyun, Daesun Yang, Junghee Lee, Hyoyoung |
description | A novel and facile method to synthesize graphene quantum dots (GQDs) from graphene oxide (GO)
via
sonication or UV-irradiation reaction using an acid-free oxone oxidant (potassium monopersulfate) that does not require a neutralization process with a strong base was developed. Our novel sono- and photo-oxidation approach yielded high quality GQDs after simple purification. GO sheets treated by sono- and photo-oxidation with the oxone oxidant as the free radical source broke in multiple places for efficient generation of GQDs. Sono-oxidation is a simpler and more facile method than photo-oxidation in terms of mass production and the strong fluorescence properties of the resulting GQDs. Facile synthesis by sono- and photo-oxidation represents a new route to prepare GQDs from GO in organic solvent.
Facile synthesis of graphene quantum dots using an acid-free oxone oxidant and graphene oxide was successfully developed by sono- and photo-oxidation reactions. |
doi_str_mv | 10.1039/c4nj02299h |
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via
sonication or UV-irradiation reaction using an acid-free oxone oxidant (potassium monopersulfate) that does not require a neutralization process with a strong base was developed. Our novel sono- and photo-oxidation approach yielded high quality GQDs after simple purification. GO sheets treated by sono- and photo-oxidation with the oxone oxidant as the free radical source broke in multiple places for efficient generation of GQDs. Sono-oxidation is a simpler and more facile method than photo-oxidation in terms of mass production and the strong fluorescence properties of the resulting GQDs. Facile synthesis by sono- and photo-oxidation represents a new route to prepare GQDs from GO in organic solvent.
Facile synthesis of graphene quantum dots using an acid-free oxone oxidant and graphene oxide was successfully developed by sono- and photo-oxidation reactions.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/c4nj02299h</identifier><language>eng</language><creationdate>2015-03</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Shin, Yonghun</creatorcontrib><creatorcontrib>Park, Jintaek</creatorcontrib><creatorcontrib>Hyun, Daesun</creatorcontrib><creatorcontrib>Yang, Junghee</creatorcontrib><creatorcontrib>Lee, Hyoyoung</creatorcontrib><title>Generation of graphene quantum dots by the oxidative cleavage of graphene oxide using the oxone oxidantElectronic supplementary information (ESI) available. See DOI: 10.1039/c4nj02299h</title><description>A novel and facile method to synthesize graphene quantum dots (GQDs) from graphene oxide (GO)
via
sonication or UV-irradiation reaction using an acid-free oxone oxidant (potassium monopersulfate) that does not require a neutralization process with a strong base was developed. Our novel sono- and photo-oxidation approach yielded high quality GQDs after simple purification. GO sheets treated by sono- and photo-oxidation with the oxone oxidant as the free radical source broke in multiple places for efficient generation of GQDs. Sono-oxidation is a simpler and more facile method than photo-oxidation in terms of mass production and the strong fluorescence properties of the resulting GQDs. Facile synthesis by sono- and photo-oxidation represents a new route to prepare GQDs from GO in organic solvent.
Facile synthesis of graphene quantum dots using an acid-free oxone oxidant and graphene oxide was successfully developed by sono- and photo-oxidation reactions.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj0FLxDAQhYMouK5evAvjTQ9dk7ZW4lWr7snDei_ZdNpmSZOapIv7z_x5RiyICHqa4b03H28IOWV0wWjGr2RuNjRNOe_2yIxlBU94WrD9uLM8T-h1XhySI-83lDJ2U7AZeX9Eg04EZQ3YBlonhi4q8DoKE8Yeahs8rHcQOgT7puqY3CJIjWIrWvxx8mkjjF6ZdorbSY2oUqMMzholwY_DoLFHE4TbgTKNdf1XgYtytbyESFZarDUuYIUI98_LW_j93zE5aIT2eDLNOTl7KF_unhLnZTU41Ud49R3P5uT8L78a6ib7j_EBVPlwgg</recordid><startdate>20150331</startdate><enddate>20150331</enddate><creator>Shin, Yonghun</creator><creator>Park, Jintaek</creator><creator>Hyun, Daesun</creator><creator>Yang, Junghee</creator><creator>Lee, Hyoyoung</creator><scope/></search><sort><creationdate>20150331</creationdate><title>Generation of graphene quantum dots by the oxidative cleavage of graphene oxide using the oxone oxidantElectronic supplementary information (ESI) available. See DOI: 10.1039/c4nj02299h</title><author>Shin, Yonghun ; Park, Jintaek ; Hyun, Daesun ; Yang, Junghee ; Lee, Hyoyoung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c4nj02299h3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shin, Yonghun</creatorcontrib><creatorcontrib>Park, Jintaek</creatorcontrib><creatorcontrib>Hyun, Daesun</creatorcontrib><creatorcontrib>Yang, Junghee</creatorcontrib><creatorcontrib>Lee, Hyoyoung</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shin, Yonghun</au><au>Park, Jintaek</au><au>Hyun, Daesun</au><au>Yang, Junghee</au><au>Lee, Hyoyoung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Generation of graphene quantum dots by the oxidative cleavage of graphene oxide using the oxone oxidantElectronic supplementary information (ESI) available. See DOI: 10.1039/c4nj02299h</atitle><date>2015-03-31</date><risdate>2015</risdate><volume>39</volume><issue>4</issue><spage>2425</spage><epage>2428</epage><pages>2425-2428</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>A novel and facile method to synthesize graphene quantum dots (GQDs) from graphene oxide (GO)
via
sonication or UV-irradiation reaction using an acid-free oxone oxidant (potassium monopersulfate) that does not require a neutralization process with a strong base was developed. Our novel sono- and photo-oxidation approach yielded high quality GQDs after simple purification. GO sheets treated by sono- and photo-oxidation with the oxone oxidant as the free radical source broke in multiple places for efficient generation of GQDs. Sono-oxidation is a simpler and more facile method than photo-oxidation in terms of mass production and the strong fluorescence properties of the resulting GQDs. Facile synthesis by sono- and photo-oxidation represents a new route to prepare GQDs from GO in organic solvent.
Facile synthesis of graphene quantum dots using an acid-free oxone oxidant and graphene oxide was successfully developed by sono- and photo-oxidation reactions.</abstract><doi>10.1039/c4nj02299h</doi><tpages>4</tpages></addata></record> |
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title | Generation of graphene quantum dots by the oxidative cleavage of graphene oxide using the oxone oxidantElectronic supplementary information (ESI) available. See DOI: 10.1039/c4nj02299h |
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