Influence of ligand environment on the structure and properties of silver(i) dithiocarbamate cluster-based coordination polymers and dimersElectronic supplementary information (ESI) available: ORTEP diagram of 2 and 3, 31P NMR spectra of complexes 3 and 4, bond lengths (Å) and angles (°) for complexes 3 and 4, photophysical data of complexes, TGA results for the complexes (2, 4). CCDC 934751 (1), 934752 (2), 989805 (3) and 934753 (4). For ESI and crystallographic data in CIF or other electronic
Luminescent silver( i ) homo- and heteroleptic pyridyl functionalised dithiocarbamate (dtc) complexes of the form, [{Ag(L)} 4 ] ∞ (L = N -benzyl- N -methylpyridyldtc (L1) 1 , bis-( N -methylpyridyl)dtc (L2) 2 ) and [Ag(L)PPh 3 ] 2 (L = L1 ( 3 ), L2 ( 4 )) have been synthesized and characterized by e...
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