Heterometallic complexes combining [MnIII(salpn)]+ and [Fe(CN)6]4− units as the products of reactions between [MnIII(salpn)(H2O)C(CN)3] and [Fe(CN)6]3−/4−Electronic supplementary information (ESI) available: Fig S1-S6. CCDC 986574 (2), 986575 (3) and 986576 (4). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4nj00427b
The reaction of [Fe( iii )(CN) 6 ] 3− with neutral [Mn(salpn)(H 2 O)C(CN) 3 ] (salpn: N,N ′-propylenebis(salicylideneiminato)) ( 1 ) produces two new heterometallic complexes [{Mn III (salpn)(H 2 O)} 2 {Mn III (salpn)(H 2 O) 0.7 (CH 3 OH) 0.3 } 2 Fe II (CN) 6 ]· n (H 2 O/CH 3 OH) ( 2 ) and [{Mn III...
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