1,2,3-Triazolylidene ruthenium(ii)-cyclometalated complexes and olefin selective hydrogenation catalysisElectronic supplementary information (ESI) available. CCDC 1028679-1028683. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt03156c
Silver( i ) 1,2,3-triazol-5-ylidenes [(RCH 2 C 2 N 2 (NMe)Ph) 2 Ag][AgCl 2 ] (R = Ph 3a , C 6 H 2 iPr 3 3b , C 6 H 2 Me 3 3c ) and [(PhCH 2 C 2 N 2 (NMe)R) 2 Ag][AgCl 2 ] (R = C 6 H 4 Me 3d , C 6 H 4 CF 3 3e ) were synthesized and subsequently treated with RuHCl(PPh 3 ) 3 and RuHCl(H 2 )(PCy 3 ) 2 ....
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