Synthesis, structure and reactivity study of magnesium amidinato complexes derived from carbodiimides and N,N′-bis(2,6-diisopropylphenyl)-1,4-diaza-butadiene ligandsElectronic supplementary information (ESI) available. CCDC 1019669-1019675. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt03074e
We report an amidinato ligand-supported series of magnesium complexes obtained from the insertion of a magnesium-carbon bond into a carbon-nitrogen double bond of different carbodiimides and α-diimine ligands. The magnesium complexes [Mg(CH 2 Ph){CyN&z.dbd;C(CH 2 Ph)NCy}] 2 ( 1 ), [Mg(CH 2 Ph){...
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