Formation, structural characterization, and reactions of a unique cyclotrimeric vicinal Lewis pair containing (C6F5)2P-Lewis base and (C6F5)BH-Lewis acid componentsElectronic supplementary information (ESI) available: Experimental, analytical details and crystallographic data. CCDC 1001587-1001589. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt02081b

The synthesis of the new vicinal frustrated Lewis pair 5 containing (C 6 F 5 ) 2 P-Lewis base and (C 6 F 5 )BH-Lewis acid functionality is described. It forms a unique cyclotrimer ( 5 ) 3 which was structurally characterized by X-ray crystallography and high-resolution solid-state NMR spectroscopy....

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Hauptverfasser: Erdmann, Markus, Wiegand, Thomas, Blumenberg, Jonas, Eckert, Hellmut, Ren, Jinjun, Daniliuc, Constantin G, Kehr, Gerald, Erker, Gerhard
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Sprache:eng
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