Protonolysis and thermolysis reactions of functionalised NHC-carbene boranes and boratesElectronic supplementary information (ESI) available: Additional synthetic and crystallographic details for the complexes. CCDC 1003569-1003576. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt01464b

A set of β-ketoimidazolium and β-ketoimidazolinium salts of the general formula [R 1 C(O)CH 2 {CH[NCR 3 CR 3 N(R 2 )]}]X (R 1 = t Bu, naphth; R 2 = i Pr, Mes, t Bu; R 3 = H, Me, (H) 2 ; X = Cl, Br) show contrasting reactivity with superhydride bases MHBEt 3 ; two are reduced to chiral β-alcohol carb...

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Hauptverfasser:	Arnold, Polly L, Bell, Nicola L, Marr, Isobel H, She, Siyi, Hamilton, Jonathan, Fraser, Craig, Wang, Kai
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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