A kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexesElectronic supplementary information (ESI) available: Table S1, rate constant data for the monitored cyclometallation processes of primary amines; Table S2, rate constant data for the cyclometallation of secondary and tertiary amines; Fig. S1, Eyring plots for some of the reactions studied. CCDC 993787 and 993639. For ESI and crystallographic data in C

A kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexesElectronic supplementary information (ESI) available: Table S1, rate constant data for the monitored cyclometallation processes of primary amines; Table S2, rate constant data for the cyclometallation of secondary and tertiary amines; Fig. S1, Eyring plots for some of the reactions studied. CCDC 993787 and 993639. For ESI and crystallographic data in C

The cyclometallation reactions of dinuclear μ-acetato complexes of the type [Pd(AcO)(μ-AcO)L] 2 (L = 4-RC 6 H 4 CH 2 NH 2 , R = H, Cl, F, CF 3 ), a process found to occur readily even in the solid state, have been studied from a kinetico-mechanistic perspective. Data indicate that the dinuclear acet...

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Hauptverfasser: Font, Helena, Font-Bardia, Mercè, Gómez, Kerman, González, Gabriel, Granell, Jaume, Macho, Israel, Martínez, Manuel
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Sprache:eng
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