Assembly, characterization, and electrochemical properties of immobilized metal bipyridyl complexes on silicon(111) surfacesElectronic supplementary information (ESI) available: Detailed experimental information; additional XPS and electrochemistry data. See DOI: 10.1039/c4dt01149j
Silicon(111) surfaces have been functionalized with mixed monolayers consisting of submonolayer coverages of immobilized 4-vinyl-2,2′-bipyridyl ( 1 , vbpy) moieties, with the remaining atop sites of the silicon surface passivated by methyl groups. As the immobilized bipyridyl ligands bind transition...
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