Differences in the cyclometalation reactivity of bisphosphinimine-supported organo-rare earth complexesElectronic supplementary information (ESI) available: Atomic coordinates, interatomic distances and angles, anisotropic thermal parameters, and hydrogen parameters for 1, 2, 3, 4, and 5. CCDC 991840-991844 for 1-5. For crystallographic data in CIF format see DOI: 10.1039/c4dt00863d

The pyrrole-based ligand N , N ′-((1 H -pyrrole-2,5-diyl)bis(diphenylphosphoranylylidene))bis(4-isopropylaniline) (H L B ) can be deprotonated and coordinated to yttrium and samarium ions upon reaction with their respective trialkyl precursors. In the case of yttrium, the resulting complex [ L B Y(C...

Ausführliche Beschreibung

Bibliographische Detailangaben

Hauptverfasser:	Zamora, Matthew T, Johnson, Kevin R. D, Hänninen, Mikko M, Hayes, Paul G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!