Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerizationElectronic supplementary information (ESI) available. CCDC 982911-982916. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt00242c
A series of rare-earth metal monoalkyl complexes supported by N , N ′-di(2,6-dialkylphenyl)formamidinate ligand (L) 2 RECH 2 SiMe 3 ·thf [L 1 = HC(N-2,6-Me 2 C 6 H 3 ) 2 , RE = Y ( 1 ), L 2 = HC(N-2,6- i Pr 2 C 6 H 3 ) 2 , RE = Y ( 2 ), Er ( 3 ), Dy ( 4 ), Sm ( 5 ), and Nd ( 6 )] were synthesized by...
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