On the relation of energy and electron transfer in multidimensional chromophores based on polychlorinated triphenylmethyl radicals and triarylaminesElectronic supplementary information (ESI) available: Discussion of synthesis, NMR spectra of HAB-S, HAB-A and HAB-Model, discussion of electrochemistry, electron paramagnetic resonance and spectroelectrochemistry data, transient absorption raw data, experimental part, MatLab script for global analysis. See DOI: 10.1039/c4cp05929h

A star-like compound consisting of a polychlorinated triphenylmethyl radical (PCTM) core linked to three triarylamines (TAA) and a symmetric and an asymmetric hexaarylbenzene (HAB) both substituted with three PCTMs and three TAAs were synthesised. In the star-like compound a strong communication bet...

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Hauptverfasser: Steeger, Markus, Griesbeck, Stefanie, Schmiedel, Alexander, Holzapfel, Marco, Krummenacher, Ivo, Braunschweig, Holger, Lambert, Christoph
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Sprache:eng
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