Nucleofugality in oxygen and nitrogen derived pseudohalides in Menshutkin reactions: the importance of the intrinsic barrierWe dedicate this work to the memory of Gregory L. Baker, who was a mentor, colleague and friend.Electronic supplementary information (ESI) available. See DOI: 10.1039/c4cp03741c
In order to study the nucleofugality of polyatomic anionic leaving groups derived from oxygen and nitrogen, a contingent of 19 methylating agents consisting of amines or alcohols activated with carbonyl or sulfonyl substituents has been examined via ab initio calculations. We have calculated gas pha...
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