Rigid yet flexible heteroleptic Co(iii) dipyrrin complexes for the construction of heterometallic 1- and 2-D coordination polymersCCDC 984811-984820. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ce00273c
A series of four discrete complexes of the (acac)Co(dpm) 2 or (hfac)Co(dpm) 2 type incorporating either the 3- or 4-pyridyl appended dipyrrin (dpm) ligand has been prepared, characterized and employed as metallatectons for the construction of heterometallic coordination polymers (CPs) upon combinati...
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