Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monolithsElectronic supplementary information (ESI) available: Experimental details, an SEM image, and pore properties obtained from nitrogen adsorption-desorption. See DOI: 10.1039/c4cc09694k
The synthesis of highly crystalline macro-meso-microporous monolithic Cu 3 (btc) 2 (HKUST-1; btc 3− = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH) 2 -based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monolit...
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creator | Moitra, Nirmalya Fukumoto, Shotaro Reboul, Julien Sumida, Kenji Zhu, Yang Nakanishi, Kazuki Furukawa, Shuhei Kitagawa, Susumu Kanamori, Kazuyoshi |
description | The synthesis of highly crystalline macro-meso-microporous monolithic Cu
3
(btc)
2
(HKUST-1; btc
3−
= benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)
2
-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.
Robust, hierarchically porous Cu
3
(btc)
2
(HKUST-1, btc
3−
= benzene-1,3,5-tricalboxylate) monoliths have been synthesized by direct conversion of sol-gel-derived Cu(OH)
2
-based monoliths. |
doi_str_mv | 10.1039/c4cc09694k |
format | Article |
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3
(btc)
2
(HKUST-1; btc
3−
= benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)
2
-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.
Robust, hierarchically porous Cu
3
(btc)
2
(HKUST-1, btc
3−
= benzene-1,3,5-tricalboxylate) monoliths have been synthesized by direct conversion of sol-gel-derived Cu(OH)
2
-based monoliths.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c4cc09694k</identifier><language>eng</language><creationdate>2015-02</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Moitra, Nirmalya</creatorcontrib><creatorcontrib>Fukumoto, Shotaro</creatorcontrib><creatorcontrib>Reboul, Julien</creatorcontrib><creatorcontrib>Sumida, Kenji</creatorcontrib><creatorcontrib>Zhu, Yang</creatorcontrib><creatorcontrib>Nakanishi, Kazuki</creatorcontrib><creatorcontrib>Furukawa, Shuhei</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Kanamori, Kazuyoshi</creatorcontrib><title>Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monolithsElectronic supplementary information (ESI) available: Experimental details, an SEM image, and pore properties obtained from nitrogen adsorption-desorption. See DOI: 10.1039/c4cc09694k</title><description>The synthesis of highly crystalline macro-meso-microporous monolithic Cu
3
(btc)
2
(HKUST-1; btc
3−
= benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)
2
-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.
Robust, hierarchically porous Cu
3
(btc)
2
(HKUST-1, btc
3−
= benzene-1,3,5-tricalboxylate) monoliths have been synthesized by direct conversion of sol-gel-derived Cu(OH)
2
-based monoliths.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUM9PwjAUnkYTEb14N3neRsKQuQ0ZiSecwRjiAUy8kdK-sWrXNm0h8N_bGQwHE-3l_fre932vQXAV93txP8lvaUppPx_k6edx0IqTQRpl6fD9pMmzPLpP0uwsOLf2o-9fnA1bRw9TpBWRnBIhdmAdWQrsQsXREEOrfVsro9YWxuskXDrauYNw8vI2m0dxB2olleCusrDhBBg3SB1QJTdoLFcSVOkrrdGEnHeg2jGjtpxhtCQW2WG7EH7PKO8D7FprgTVKR8wOuCyVqYlruMJi9twBsiFcNDZHUGw9Mf-GCmDo_MB2gUiYFVPgNVlhU7HGP4I2yqMdRwtq6aHS65dG1SC5V16hBMKsMrqRihj-pD2YIcLj6_MIfn_yRXBaEmHxch_bwfVTMR9PImPpQntr_oTFAZ60g5u_5gvNyuQ_ji9Li5_b</recordid><startdate>20150212</startdate><enddate>20150212</enddate><creator>Moitra, Nirmalya</creator><creator>Fukumoto, Shotaro</creator><creator>Reboul, Julien</creator><creator>Sumida, Kenji</creator><creator>Zhu, Yang</creator><creator>Nakanishi, Kazuki</creator><creator>Furukawa, Shuhei</creator><creator>Kitagawa, Susumu</creator><creator>Kanamori, Kazuyoshi</creator><scope/></search><sort><creationdate>20150212</creationdate><title>Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monolithsElectronic supplementary information (ESI) available: Experimental details, an SEM image, and pore properties obtained from nitrogen adsorption-desorption. See DOI: 10.1039/c4cc09694k</title><author>Moitra, Nirmalya ; Fukumoto, Shotaro ; Reboul, Julien ; Sumida, Kenji ; Zhu, Yang ; Nakanishi, Kazuki ; Furukawa, Shuhei ; Kitagawa, Susumu ; Kanamori, Kazuyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c4cc09694k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moitra, Nirmalya</creatorcontrib><creatorcontrib>Fukumoto, Shotaro</creatorcontrib><creatorcontrib>Reboul, Julien</creatorcontrib><creatorcontrib>Sumida, Kenji</creatorcontrib><creatorcontrib>Zhu, Yang</creatorcontrib><creatorcontrib>Nakanishi, Kazuki</creatorcontrib><creatorcontrib>Furukawa, Shuhei</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Kanamori, Kazuyoshi</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moitra, Nirmalya</au><au>Fukumoto, Shotaro</au><au>Reboul, Julien</au><au>Sumida, Kenji</au><au>Zhu, Yang</au><au>Nakanishi, Kazuki</au><au>Furukawa, Shuhei</au><au>Kitagawa, Susumu</au><au>Kanamori, Kazuyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monolithsElectronic supplementary information (ESI) available: Experimental details, an SEM image, and pore properties obtained from nitrogen adsorption-desorption. See DOI: 10.1039/c4cc09694k</atitle><date>2015-02-12</date><risdate>2015</risdate><volume>51</volume><issue>17</issue><spage>3511</spage><epage>3514</epage><pages>3511-3514</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The synthesis of highly crystalline macro-meso-microporous monolithic Cu
3
(btc)
2
(HKUST-1; btc
3−
= benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)
2
-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.
Robust, hierarchically porous Cu
3
(btc)
2
(HKUST-1, btc
3−
= benzene-1,3,5-tricalboxylate) monoliths have been synthesized by direct conversion of sol-gel-derived Cu(OH)
2
-based monoliths.</abstract><doi>10.1039/c4cc09694k</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
title | Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monolithsElectronic supplementary information (ESI) available: Experimental details, an SEM image, and pore properties obtained from nitrogen adsorption-desorption. See DOI: 10.1039/c4cc09694k |
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